102431 | Chloroform

102431
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      Overview

      Replacement Information

      Key Spec Table

      CAS # EC Number Hill Formula Chemical Formula Molar Mass Grade Value
      67-66-3200-663-8CHCl₃CHCl₃119.38 g/molBP

      Pricing & Availability

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      1024311000
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          Glass bottle 1 l
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          1024312500
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              Glass bottle 2.5 l
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              1024316025
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                  Drum stainl. st. 25 l
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                  1024319190
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                      Steel barrel 190 l
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                      Description
                      Catalogue Number 102431
                      Synonyms TCM, Trichloromethane, Methane trichloride, Methyl trichloride
                      References
                      Product Information
                      CAS number 67-66-3
                      EC index number 602-006-00-4
                      EC number 200-663-8
                      Grade BP
                      Hill Formula CHCl₃
                      Chemical formula CHCl₃
                      Molar Mass 119.38 g/mol
                      HS Code 2903 13 00
                      Structure formula Image
                      Applications
                      Biological Information
                      Physicochemical Information
                      Boiling point 61 °C (1013 hPa)
                      Density 1.48 g/cm³ (20 °C)
                      Melting Point -63 °C
                      Vapor pressure 211 hPa (20 °C)
                      Refractive Index 1.45
                      Solubility 8 g/l (20 °C)
                      Dimensions
                      Materials Information
                      Toxicological Information
                      LD 50 oral LD50 Rat 695 mg/kg
                      LD 50 dermal LD50 Rabbit > 3980 mg/kg
                      Safety Information according to GHS
                      Hazard Pictogram(s)

                      Hazard Statement(s) H302: Harmful if swallowed.
                      H315: Causes skin irritation.
                      H319: Causes serious eye irritation.
                      H331: Toxic if inhaled.
                      H351: Suspected of causing cancer.
                      H361d: Suspected of damaging the unborn child.
                      H372: Causes damage to organs (/$/*_ORGAN_REPEAT/$/) through prolonged or repeated exposure.
                      Precautionary Statement(s) P281: Use personal protective equipment as required.
                      P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
                      P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
                      P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
                      P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
                      Signal Word Danger
                      RTECS FS9100000
                      Storage class 6.1 D Non combustible, acute toxicity cat. 3 / toxic or substances with chronic effects
                      WGK WGK 3 highly water endangering
                      Disposal 2
                      Organic halogenated solvents and solutions of organic halogen-containing substances: For strongly contaminated or mixed halogenated solvents container B: Caution: Do not use aluminium containers; in addition, in the case of water-containing chlorinated waste materials do not use stainless-steel containers (danger of leaks caused by corrosion).
                      Safety Information
                      Hazard Symbols Harmful
                      Categories of danger harmful, irritant, carcinogenic, toxic for reproduction
                      R Phrase R 20/22-36/38-40-48/20-63
                      Harmful by inhalation and if swallowed.Irritating to eyes and skin.Limited evidence of a carcinogenic effect.Harmful: danger of serious damage to health by prolonged exposure through inhalation.Possible risk of harm to the unborn child.
                      S Phrase S 36/37
                      Wear suitable protective clothing and gloves.
                      Product Usage Statements
                      Storage and Shipping Information
                      Packaging Information
                      Transport Information
                      Declaration (railroad and road) ADR, RID UN 1888 Chloroform, 6.1, III
                      Declaration (transport by air) IATA-DGR UN 1888 CHLOROFORM, 6.1, III
                      Declaration (transport by sea) IMDG-Code UN 1888 CHLOROFORM, 6.1, III, Segregation Group: 10 (Liquid halogenated hydrocarbons)
                      Supplemental Information
                      Specifications
                      Specifications
                      Purity (GC)99.0 - 99.4 % (w/w)
                      Identity (IR)conforms
                      Acidity or alkalinityconforms
                      Density (d 20 °C/ 4 °C)1.474 - 1.479
                      Density (d 20 °C/20 °C)1.479 - 1.482
                      Boiling range (60-62°C)≥ 95 % (v/v)
                      Chloride (Cl)conforms
                      Free chlorine (as Cl)conforms
                      Ethanol (GC)1.0 - 2.0 % (v/v)
                      Related substances (GC)≤ 1.0 % (v/v)
                      Bromochloromethane (GC)≤ 0.01 %
                      1,2-Dichloroethene (GC)≤ 0.05 %
                      Dichloromethane (GC)≤ 0.01 %
                      Carbon tetrachloride (GC)≤ 0.01 %
                      1,1,2-Trichloroethene (GC)≤ 0.01 %
                      Other residual solvents (ICH Q3C)excluded by manufacturing process
                      Aldehydesconforms
                      Foreign chlorine compoundsconforms
                      Matter discoloured by H₂SO₄≤ 10 Hazen
                      Evaporation residue≤ 0.0010 %
                      Water≤ 0.10 %
                      Residues of metal catalysts or metal reagents acc. to EMEA/CHMP/SWP/4446/2000 are not likely to be present.
                      Stabilized with 1,0 - 2,0% V/V ethanol
                      Conforms to BP

                      Documentation

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                      Certificates of Analysis

                      Product Number Packaging Specification Lot Number
                      1024311000 Glass bottle PDF Specification Document
                      1024312500 Glass bottle PDF Specification Document
                      1024316025 Drum stainl. st. PDF Specification Document
                      1024319190 Steel barrel PDF Specification Document

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