814147 tert-Butyllithium

814147
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      Overview

      Replacement Information

      Key Spec Table

      Pricing & Availability

      Catalogue NumberAvailability Packaging Qty/Pack Price Quantity
      8141470100
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      In Stock 
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          Glass bottle 100 ml
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          Description
          Catalogue Number814147
          SynonymsLithium-tert-butyl
          References
          Product Information
          HS Code2931 90 00
          Structure formula ImageStructure formula Image
          Applications
          Biological Information
          Physicochemical Information
          Boiling point36 °C (1013 hPa) (Pentane)
          Density0.63 g/cm3 (20 °C)
          Explosion limit1.4 - 7.8 %(V) (Pentane)
          Flash point-48 °C (Pentane)
          Ignition temperature285 °C (Pentane)
          Melting Point-130 °C (Pentane)
          pH value>7 (H₂O, 20 °C)
          Vapor pressure573 hPa (20 °C)
          Dimensions
          Materials Information
          Toxicological Information
          Safety Information according to GHS
          Hazard Pictogram(s) Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Statement(s)H225: Highly flammable liquid and vapour.
          H250: Catches fire spontaneously if exposed to air.
          H260: In contact with water releases flammable gases which may ignite spontaneously.
          H304: May be fatal if swallowed and enters airways.
          H314: Causes severe skin burns and eye damage.
          H336: May cause drowsiness or dizziness.
          H411: Toxic to aquatic life with long lasting effects.
          EUH014: Reacts violently with water.
          Precautionary Statement(s)P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking.
          P273: Avoid release to the environment.
          P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
          P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor.
          P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
          P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
          P370 + P378: In case of fire: Use sand for extinction.
          P402 + P404: Store in a dry place. Store in a closed container.
          P422: Store contents under inert gas.
          Signal WordDanger
          Storage class4.2 Pyrophoric and self-heating hazardous materials
          WGKWGK 2 obviously hazardous to water
          Disposal8
          Hydrolysis-sensitive organoelement compounds and metal alkyls, which are as a rule dissolved in organic solvents, should be carefully stirred dropwise into 1-butanol (Cat. No. 822262) in a hood with the front screen closed. Any flammable gases formed should be fed via a tube directly into the extractor duct. When gas development has ceased, continue stirring for one hour and add an excess of water. Container A.
          Safety Information
          Hazard Symbols Hazard SymbolsCorrosive
          Hazard SymbolsFlammable
          Hazard SymbolsDangerous for the environment
          Categories of dangerhighly flammable, corrosive, dangerous for the environment, harmful
          R PhraseR 11-14/15-17-34-51/53-65-67
          Highly flammable.Reacts violently with water, liberating extremely flammable gases.Spontaneously flammable in air.Causes burns.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Harmful: may cause lung damage if swallowed.Vapours may cause drowsiness and dizziness.
          S PhraseS 6-16-26-33-36/37/39-43-45-61-62
          Keep under protective gas.Keep away from sources of ignition - No smoking.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take precautionary measures against static discharges.Wear suitable protective clothing, gloves and eye/face protection.In case of fire, use metal-fire powder. Never use water.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/ Safety data sheets.If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
          Product Usage Statements
          Storage and Shipping Information
          StorageStore at <= 20°C.
          Packaging Information
          Transport Information
          Declaration (railroad and road) ADR, RIDUN 3394 , 4.2 (4.3), I
          Declaration (transport by air) IATA-DGRUN 3394 , 4.2 (4.3),
          Declaration (transport by sea) IMDG-CodeUN 3394 , 4.2 (4.3), I
          Supplemental Information
          Specifications
          Assay (acidimetric)14.5 - 19.5 %
          Assay (total alcalinity)14.5 - 19.5 %

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          Categories

          Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Organoelement Compounds > Organometal Compounds
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          Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Reagents for Organometallic Synthesis
          Reagents, Chemicals and Labware > Organic Synthesis > Product Line "for synthesis" > Reagents for Organometallic Synthesis
          Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Organoelement Compounds > Organometal Compounds