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105227  Cupferron
GR for analysis ACS

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19 June 2013

loading
 
Product number Packaging Qty/Pk Quantity Price
1052270025  Glass bottle   25 g  loading
1052270100  Glass bottle   100 g  loading
Prices are subject to change without notice.
Product information
Grade ACS
Synonyms Copperone, N-Nitrosophenylhydroxylamine ammonium salt, N-Phenyl-N-nitrosohydroxylamine ammonium salt
Hill Formula C6H9N3O2
HS Code 2928 00 90
EC number 205-183-2
Molar mass 155.16 g/mol
CAS number 135-20-6
Chemical and physical data
Solubility (20 °C) soluble
Melting point 153 - 155 °C (decomposition)
Molar mass 155.16 g/mol
Bulk density 460 kg/m3
Safety information according to GHS
Hazard Statement(s) H301: Toxic if swallowed.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H341: Suspected of causing genetic defects.
H350: May cause cancer.
Precautionary Statement(s) P201: Obtain special instructions before use.
P281: Use personal protective equipment as required.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P309 + P310: IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.
Signal Word Danger
Hazard Pictogram(s)
Storage class 6.1C Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK WGK 3 highly water endangering
Disposal 9
Carcinogenic compounds and flammable compounds labelled "Highly toxic" or "Toxic": container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535).
Safety information
R Phrase R 45-25-36/37-68
May cause cancer.Also toxic if swallowed.Irritating to eyes and respiratory system.Possible risk of irreversible effects.
S Phrase S 53-36/37-45
Avoid exposure - obtain special instructions before use.Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Categories of danger carcinogenic, toxic, irritant, mutagenic
Hazard Symbol
Toxic
Transport information
Declaration (railroad and road) ADR, RID UN 2811 Giftiger organischer fester Stoff, n.a.g.(KUPFERRON), 6.1, III
Declaration (transport by sea) IMDG-Code UN 2811 TOXIC SOLID, ORGANIC, N.O.S.(CUPFERRON), 6.1, III
Declaration (transport by air) IATA-DGR UN 2811 TOXIC SOLID, ORGANIC, N.O.S.(CUPFERRON), 6.1, III
Toxicological data
LD 50 oral LD50 rat 199 mg/kg
Cupferron, molecular structure

© Merck KGaA, Darmstadt, Germany, 2013


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