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106727  Nickel(II) sulfate hexahydrate
for analysis EMSURE® ACS

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Merck KGaA
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Germany
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21 April 2014

loading
 
Product number Packaging Qty/Pk Quantity Price
1067270100  Plastic bottle   100 g  loading
1067270250  Plastic bottle   250 g  loading
1067271000  Plastic bottle   1 kg  loading
Prices are subject to change without notice.
Product information
Grade ACS
Hill Formula NiO4S * 6 H2O
Chemical formula NiSO4 * 6 H2O
HS Code 2833 24 00
EC number 232-104-9
Molar mass 262.86 g/mol
EC index number 028-009-00-5
CAS number 10101-97-0
Chemical and physical data
Solubility 650 g/l (20 °C)
Melting point 53 °C
Molar mass 262.86 g/mol
Density 2.07 g/cm3 (20 °C)
Bulk density 1000 kg/m3
pH value 4.3 - 4.7 (100 g/l, H2O, 20 °C)
Safety information according to GHS
Hazard Statement(s) H350i: May cause cancer by inhalation.
H360D: May damage the unborn child.
H302: Harmful if swallowed.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H332: Harmful if inhaled.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H341: Suspected of causing genetic defects.
H372: Causes damage to organs through prolonged or repeated exposure.
H410: Very toxic to aquatic life with long lasting effects.
Precautionary Statement(s) P201: Obtain special instructions before use.
P273: Avoid release to the environment.
P280: Wear protective gloves.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
Signal Word Danger
Hazard Pictogram(s)
Storage class 6.1 D Non combustible, acute toxicity cat. 3 / toxic or substances with chronic effects
WGK WGK 3 highly water endangering
Disposal 15
Heavy metal-containing solutions and solids: container E. Stir Raney nickel (also: Urushibara nickel) in the form of an aqueous suspension into hydrochloric acid (Cat. No. 100312) until dissolved (container E). Neither Raney nickel itself nor any filter residues should be allowed to dry out, otherwise they will spontaneously ignite in air. In this context, heavy metal means any compound of antimony, arsenic, cadmium, chromium(VI), copper, lead, nickel and tin, as well as these subtances in metallic form, if they are classified as hazardous (acc. to AbfallverzeichnisV - Waste Catalogue Ordinance, Appendix 3). Other heavy metals should be collected separately.
Safety information
R Phrase R 49-61-20/22-48/23-38-68-42/43-50/53
May cause cancer by inhalation.May cause harm to the unborn child.Also harmful by inhalation and if swallowed.Also toxic: danger of serious damage to health by prolonged exposure through inhalation.Irritating to skin.Possible risk of irreversible effects.May cause sensitisation by inhalation and skin contact.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S Phrase S 53-45-60-61
Avoid exposure - obtain special instructions before use.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste.Avoid release to the environment. Refer to special instructions/ Safety data sheets.
Categories of danger carcinogenic, toxic for reproduction, toxic, irritant, mutagenic, sensitizing, dangerous for the environment
Hazard Symbol
Toxic
Dangerous for the environment
Transport information
Declaration (railroad and road) ADR, RID UN 3077 Umweltgefährdender Stoff, fest, n.a.g.(NICKEL(II) SULFAT HEXAHYDRAT), 9, III
Declaration (transport by sea) IMDG-Code UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.(NICKEL(II) SULFATE HEXAHYDRATE), 9, III, Marine Pollutant: P
Declaration (transport by air) IATA-DGR UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.(NICKEL(II) SULFATE HEXAHYDRATE), 9, III
Toxicological data
LD 50 oral LD50 rat 361 mg/kg

© Merck KGaA, Darmstadt, Germany, 2014


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