Nickel(II) sulfate hexahydrate
for analysis EMSURE® ACS
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21 April 2014
|Hill Formula||NiO4S * 6 H2O|
|Chemical formula||NiSO4 * 6 H2O|
|HS Code||2833 24 00|
|Molar mass||262.86 g/mol|
|EC index number||028-009-00-5|
|Chemical and physical data|
|Solubility||650 g/l (20 °C)|
|Melting point||53 °C|
|Molar mass||262.86 g/mol|
|Density||2.07 g/cm3 (20 °C)|
|Bulk density||1000 kg/m3|
|pH value||4.3 - 4.7 (100 g/l, H2O, 20 °C)|
|Safety information according to GHS|
H350i: May cause cancer by inhalation.
H360D: May damage the unborn child.
H302: Harmful if swallowed.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H332: Harmful if inhaled.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H341: Suspected of causing genetic defects.
H372: Causes damage to organs through prolonged or repeated exposure.
H410: Very toxic to aquatic life with long lasting effects.
P201: Obtain special instructions before use.
P273: Avoid release to the environment.
P280: Wear protective gloves.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
|Storage class||6.1 D Non combustible, acute toxicity cat. 3 / toxic or substances with chronic effects|
|WGK||WGK 3 highly water endangering|
Heavy metal-containing solutions and solids: container E. Stir Raney nickel (also: Urushibara nickel) in the form of an aqueous suspension into hydrochloric acid (Cat. No. 100312) until dissolved (container E). Neither Raney nickel itself nor any filter residues should be allowed to dry out, otherwise they will spontaneously ignite in air. In this context, heavy metal means any compound of antimony, arsenic, cadmium, chromium(VI), copper, lead, nickel and tin, as well as these subtances in metallic form, if they are classified as hazardous (acc. to AbfallverzeichnisV - Waste Catalogue Ordinance, Appendix 3). Other heavy metals should be collected separately.
May cause cancer by inhalation.May cause harm to the unborn child.Also harmful by inhalation and if swallowed.Also toxic: danger of serious damage to health by prolonged exposure through inhalation.Irritating to skin.Possible risk of irreversible effects.May cause sensitisation by inhalation and skin contact.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid exposure - obtain special instructions before use.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste.Avoid release to the environment. Refer to special instructions/ Safety data sheets.
|Categories of danger||carcinogenic, toxic for reproduction, toxic, irritant, mutagenic, sensitizing, dangerous for the environment|
|Declaration (railroad and road) ADR, RID||UN 3077 Umweltgefährdender Stoff, fest, n.a.g.(NICKEL(II) SULFAT HEXAHYDRAT), 9, III|
|Declaration (transport by sea) IMDG-Code||UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.(NICKEL(II) SULFATE HEXAHYDRATE), 9, III, Marine Pollutant: P|
|Declaration (transport by air) IATA-DGR||UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.(NICKEL(II) SULFATE HEXAHYDRATE), 9, III|
|LD 50 oral||LD50 rat 361 mg/kg|