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109687  n-Hexane
reference substance for gas chromatography

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19 April 2014

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Product number Packaging Qty/Pk Quantity Price
1096870005  Glass bottle   5 ml  loading
Prices are subject to change without notice.
Product information
Hill Formula C6H14
Chemical formula CH3(CH2)4CH3
HS Code 2901 10 00
EC number 203-777-6
Molar mass 86.18 g/mol
EC index number 601-037-00-0
CAS number 110-54-3
Chemical and physical data
Ignition temperature 240 °C
Solubility 0.0095 g/l (20 °C)
Melting point -94.3 °C
Molar mass 86.18 g/mol
Density 0.66 g/cm3 (20 °C)
pH value (H2O) not applicable
Boiling point 69 °C (1013 hPa)
Vapor pressure 160 hPa (20 °C)
Explosion limit 1.0 - 8.1 %(V)
Flash point -22 °C
Refractive index 1.375
Viscosity kinematic 0.50 mm2/s (20 °C)
Safety information according to GHS
Hazard Statement(s) H225: Highly flammable liquid and vapour.
H304: May be fatal if swallowed and enters airways.
H315: Causes skin irritation.
H336: May cause drowsiness or dizziness.
H361f: Suspected of damaging fertility.
H373: May cause damage to organs through prolonged or repeated exposure.
H411: Toxic to aquatic life with long lasting effects.
Precautionary Statement(s) P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P240: Ground/bond container and receiving equipment.
P273: Avoid release to the environment.
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P331: Do NOT induce vomiting.
P403 + P235: Store in a well-ventilated place. Keep cool.
Signal Word Danger
Hazard Pictogram(s)
RTECS MN9275000
Storage class 3 Flammable liquids
WGK WGK 2 water endangering
Disposal 1
Strongly contaminated halogen-free organic solvents: container A.
Safety information
R Phrase R 11-38-48/20-62-65-67-51/53
Highly flammable.Irritating to skin.Harmful: danger of serious damage to health by prolonged exposure through inhalation.Possible risk of impaired fertility.Harmful: may cause lung damage if swallowed.Vapours may cause drowsiness and dizziness.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S Phrase S 9-16-29-33-36/37-61-62
Keep container in a well-ventilated place.Keep away from sources of ignition - No smoking.Do not empty into drains.Take precautionary measures against static discharges.Wear suitable protective clothing and gloves.Avoid release to the environment. Refer to special instructions/ Safety data sheets.If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
Categories of danger highly flammable, irritant, harmful, toxic for reproduction, dangerous for the environment
Hazard Symbol
Flammable
Harmful
Dangerous for the environment
Transport information
Declaration (railroad and road) ADR, RID UN 1208 Hexane, 3, II
Declaration (transport by sea) IMDG-Code UN 1208 HEXANES, 3, II
Declaration (transport by air) IATA-DGR UN 1208 HEXANES, 3, II
Toxicological data
LD 50 oral LD50 rat 25000 mg/kg
LD 50 dermal LD50 rabbit > 2000 mg/kg
n-Hexane, molecular structure

© Merck KGaA, Darmstadt, Germany, 2014


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