101799
Nitric acid 69%
for analysis EMSURE® ACS,Reag. Ph Eur
For general questions please contact our Customer Service:
Merck KGaA
Frankfurter Str. 250
64293 Darmstadt
Germany
Phone: +49 6151 72-0
Fax: +49 6151 72 2000
01 June 2012
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Chemizorb® H+ Absorbent and neutralizer for spilled acids, with indicator |
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| Product information | |||
|---|---|---|---|
| Grade | ACS,Reag. Ph Eur | ||
| HS Code | 2808 00 00 | ||
| Chemical and physical data | |||
|---|---|---|---|
| Solubility | (20 °C) soluble | ||
| Melting point | -41 °C | ||
| Density | 1.41 g/cm3 (20 °C) | ||
| pH value | < - 1 (H2O, 20 °C) | ||
| Boiling point | 122 °C | ||
| Vapor pressure | 9.4 hPa (20 °C) | ||
| Safety information according to GHS | |||
|---|---|---|---|
| Hazard Statement(s) |
H272: May intensify fire; oxidiser. H314: Causes severe skin burns and eye damage. H290: May be corrosive to metals. |
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| Precautionary Statement(s) |
P260: Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P280: Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P309: IF exposed or if you feel unwell: P310: Immediately call a POISON CENTER or doctor/ physician. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
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| Signal Word | Danger | ||
| Hazard Pictogram(s) |
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| RTECS | QU5775000 | ||
| Storage class | 5.1B Oxidizing hazardous materials | ||
| WGK | WGK 1 slightly water endangering | ||
| Disposal |
12 Inorganic acids and anhydrides thereof should first be diluted or hydrolyzed by stirring carefully into ice water and then neutralized (protective gloves, fume cupboard!) with sodium hydroxide solution (Cat. No. 105587). Before filling into container D, check the pH with pH universal indicator strips (Cat. No. 109535). Fuming sulfuric acid should be carefully stirred dropwise into 40 % sulfuric acid (Cat. No. 109286). Ensure that plenty of ice is available for cooling! When sufficiently cool, treat the highly concentrated sulfuric acid as described above. Analogous to this procedure, other anhydrides can be converted into their corresponding acids. Acid gases (e.g. hydrogen halide, chlorine, phosgene, sulfur dioxide) can be introduced into dilute sodium hydroxide solution and after neutralization disposed of in container D. |
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| Safety information | |||
|---|---|---|---|
| R Phrase |
R 35 Causes severe burns. |
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| S Phrase |
S 23-26-36/37/39-45 Do not breathe vapour.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). |
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| Categories of danger | corrosive | ||
| Hazard Symbol |
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| Transport information | |||
|---|---|---|---|
| Declaration (railroad and road) ADR, RID | UN 2031 Salpetersäure, 8 (5.1), II | ||
| Declaration (transport by sea) IMDG-Code | UN 2031 NITRIC ACID WITH AT LEAST 65% BUT NOT MORE THAN 70%, 8 (5.1), II, Segregation Group: 1 (Acids) | ||
| Declaration (transport by air) IATA-DGR | UN 2031 NITRIC ACID, 8 (5.1), II | ||
