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Merck

901591

18-Crown-6 solution

greener alternative

1.0 M in THF, liquid

Synonym(s):

1,4,7,10,13,16-Hexaoxacyclooctadecane

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About This Item

Linear Formula:
C12H24O6
CAS Number:
UNSPSC Code:
12352005
NACRES:
NA.22
MDL number:
Form:
liquid
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Product Name

18-Crown-6 solution, 1.0 M in THF

form

liquid

reaction suitability

core: crown ether

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

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Greener Alternative Product

concentration

1.0 M in THF

density

0.944 g/mL

greener alternative category

SMILES string

O1CCOCCOCCOCCOCCOCC1

InChI

1S/C12H24O6/c1-2-14-5-6-16-9-10-18-12-11-17-8-7-15-4-3-13-1/h1-12H2

InChI key

XEZNGIUYQVAUSS-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

18-Crown-6 may be used to catalyze the N-alkylation of heterocyclic compounds and allylation of functionalized aldehydes.
Phase-transfer catalyst used in a chemoselective reduction of fused tetrazoles with NaBH4 and potassium hydroxide.
Additive for greener etherification using KF-alumina.


signalword

Danger

supp_hazards

Storage Class

3 - Flammable liquids

flash_point_f

-2.0 °F

flash_point_c

-18.88 °C

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system, Respiratory system



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