Asymmetric palladium-catalysed intramolecular Wacker-type cyclisations of unsaturated alcohols and amino alcohols.

Asymmetric palladium-catalysed intramolecular Wacker-type cyclisations of unsaturated alcohols and amino alcohols.

Molecules (Basel, Switzerland) (2013-05-28)

Jana Doháňošová, Tibor Gracza

ABSTRACT

The palladium (II)-catalysed reactions of alkenols and aminoalkenols such as oxycarbonylations or bicyclisations are powerful methods for the construction of oxygen and nitrogen-containing heterocyclic compounds. This review highlights recent progress in the development of the asymmetric palladium(II)-catalysed Wacker-type cyclisations of unsaturated polyols and aminoalcohols. The scope, limitations, and applications of these reactions are presented.

MATERIALS

Product Number

Brand

Product Description

GF92481879

Palladium, foil, 6mm disks, thickness 0.25mm, as rolled, 99.99+%

GF60234533

Palladium, foil, 8mm disks, thickness 0.25mm, as rolled, 99.99+%

GF21832747

Palladium, foil, 10mm disks, thickness 0.50mm, as rolled, 99.95%

GF59386999

Palladium, foil, 6mm disks, thickness 0.50mm, as rolled, 99.95%

267120

Sigma-Aldrich

Palladium, foil, thickness 0.025 mm, 99.9% trace metals basis

287474

Sigma-Aldrich

Palladium, foil, thickness 0.5 mm, 99.9% trace metals basis

348694

Sigma-Aldrich

Palladium, wire, diam. 0.5 mm, 99.9% trace metals basis

686468

Sigma-Aldrich

Palladium, nanopowder, <25 nm particle size (TEM), ≥99.5%

348678

Sigma-Aldrich

Palladium, foil, thickness 1.0 mm, 99.9% trace metals basis

348643

Sigma-Aldrich

Palladium, foil, thickness 0.25 mm, 99.98% trace metals basis

GF73243717

Palladium, foil, not light tested, 25x25mm, thickness 0.004mm, 99.95%

GF25956917

Palladium, wire reel, 2m, diameter 0.25mm, as drawn, 99.99+%

GF59343688

Palladium, foil, not light tested, 50x50mm, thickness 0.0125mm, 99.95%

GF81392351

Palladium, foil, not light tested, 25x25mm, thickness 0.003mm, 99.95%

GF02178761

Palladium, wire reel, 2m, diameter 0.025mm, as drawn, 99.9%

GF19701503

Palladium, wire reel, 0.5m, diameter 0.125mm, hard, 99.95%

GF31401627

Palladium, foil, not light tested, 50x50mm, thickness 0.001mm, permanent polyester support, 99.75%

GF06424398

Palladium, tube, 120mm, outside diameter 6mm, inside diameter 5mm, wall thickness 0.5mm, as drawn, 99.95%

GF19845120

Palladium, rod, 50mm, diameter 4.0mm, 99.95%

GF50988358

Palladium, foil, light tested, 25x25mm, thickness 0.025mm, as rolled, 99.99+%

GF37489540

Palladium, foil, not light tested, 100x100mm, thickness 0.025mm, as rolled, 99.95%

GF92472688

Palladium, wire reel, 0.2m, diameter 1.0mm, hard, 99.95%

GF95076625

Palladium, foil, not light tested, 150x150mm, thickness 0.03mm, as rolled, 99.95%

GF77201478

Palladium, foil, 10mm disks, thickness 0.02mm, as rolled, 99.95%

GF62759841

Palladium, foil, not light tested, 100x100mm, thickness 0.005mm, 99.95%

GF85707513

Palladium, wire reel, 0.5m, diameter 1.0mm, hard, 99.95%

GF71407650

Palladium, wire reel, 1m, diameter 0.25mm, as drawn, 99.99+%

GF62160409

Palladium, foil, light tested, 25x25mm, thickness 0.075mm, as rolled, 99.95%

GF06501990

Palladium, foil, 8mm disks, thickness 0.047mm, as rolled, 99.95%

GF67105111

Palladium, foil, 25x25mm, thickness 0.1mm, as rolled, 99.95%