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841077 Boron hydride-tetrahydrofuran complex

(stabilised) (1 molar solution in tetrahydrofuran) for synthesis

Boron hydride-tetrahydrofuran complex MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.
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841077
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      		 Glass bottle 100 ml
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      Description
      Catalogue Number841077
      References
      Product Information
      HS Code3824 99 92
      Structure formula ImageStructure formula Image
      Quality LevelMQ200
      Applications
      Biological Information
      Physicochemical Information
      Boiling point66 °C (1013 hPa) (THF)
      Density0.898 g/cm3 (20 °C)
      Explosion limit1.58 - 12.42 %(V)
      Flash point-21.7 °C
      Ignition temperature103 °C
      Dimensions
      Materials Information
      Toxicological Information
      LD 50 oralLD50 Rat > 500 - 2000 mg/kg
      Safety Information according to GHS
      Hazard Pictogram(s) Hazard Pictogram(s)
      Hazard Pictogram(s)
      Hazard Pictogram(s)
      Hazard Pictogram(s)
      Hazard Statement(s)H225: Highly flammable liquid and vapour.
      H260: In contact with water releases flammable gases which may ignite spontaneously.
      H302: Harmful if swallowed.
      H318: Causes serious eye damage.
      H335: May cause respiratory irritation.
      H336: May cause drowsiness or dizziness.
      H351: Suspected of causing cancer.
      EUH014: Reacts violently with water.
      EUH019: May form explosive peroxides.
      Precautionary Statement(s)P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
      P231 + P232: Handle and store contents under inert gas. Protect from moisture.
      P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
      P301 + P312: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
      P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
      P308 + P313: IF exposed or concerned: Get medical advice/ attention.
      P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
      Signal WordDanger
      Storage class4.3 Hazardous materials, which set free flammable gases upon contact with water
      WGKWGK 2 obviously hazardous to water
      Disposal26
      Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
      Safety Information
      Categories of dangerhighly flammable, irritant, carcinogenic, harmful
      Product Usage Statements
      Storage and Shipping Information
      StorageStore at <= 20°C.
      Packaging Information
      Transport Information
      Declaration (railroad and road) ADR, RIDUN 3399 , 4.3 (3), I
      Declaration (transport by air) IATA-DGRUN 3399 , 4.3 (3), I
      Declaration (transport by sea) IMDG-CodeUN 3399 , 4.3 (3), I
      Supplemental Information
      Specifications
      Assay (iodometric)0.8 - 1.2 mol/l
      This product contains up to 0,005M sodium borohydride as a stabilizer.
      Global Trade Item Number
      Catalogue Number GTIN
      8410770100 04022536627212

      Documentation

      Boron hydride-tetrahydrofuran complex SDS

      Title

      Safety Data Sheet (SDS) 

      Boron hydride-tetrahydrofuran complex Certificates of Analysis

      Product Number PackagingLot Number
      8410770100 Glass bottle

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      Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Heterocycles > Heterocycles with 5-membered Rings > Di- and Tetrahydrofurans, Butyrolactones
      Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Organoelement Compounds > Boric Compounds
      Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Organoelement Compounds > Boric Compounds