Glycidyl methacrylate

Name: Glycidyl methacrylate
Brand: ALDRICH

97%, contains 100 ppm monomethyl ether hydroquinone as inhibitor

Synonym(s):

2,3-Epoxypropyl methacrylate, Methacrylic acid 2,3-epoxypropyl ester

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About This Item

Empirical Formula (Hill Notation):

C₇H₁₀O₃

CAS Number:

106-91-2

Molecular Weight:

142.15

UNSPSC Code:

12162002

NACRES:

NA.23

PubChem Substance ID:

24849103

EC Number:

203-441-9

Beilstein/REAXYS Number:

2506

MDL number:

MFCD00005137

Product Name

Glycidyl methacrylate, 97%, contains 100 ppm monomethyl ether hydroquinone as inhibitor

InChI key

VOZRXNHHFUQHIL-UHFFFAOYSA-N

InChI

1S/C7H10O3/c1-5(2)7(8)10-4-6-3-9-6/h6H,1,3-4H2,2H3

SMILES string

CC(=C)C(=O)OCC1CO1

assay

97%

form

liquid

contains

100 ppm monomethyl ether hydroquinone as inhibitor

impurities

0.02% epichlorohydrin

refractive index

n20/D 1.449 (lit.)

bp

189 °C (lit.)

density

1.042 g/mL at 25 °C (lit.)

storage temp.

2-8°C

Quality Level

300

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Biomedical Materials

Monomers

Polymerization Tools

Application

Glycidyl methacrylate dextran (GMA) has been reported to be used as a biocompatible hydrogel. In situ polymerization of GMA with trimethylolpropane trimethacrylate to form macroporous sorbents has also been reported. GMA may also be grafted onto polypropylene.

General description

Glycidyl methacrylate (GMA) is a polyfunctional monomer. It acts as an adhesion promoting crosslinking co-monomer for acrylic and vinyl resins. It is also a reactive colorless diluent. GMA is soluble in ethanol, acetone, diethyl ether, benzene.

pictograms

GHS06,GHS08,GHS05

signalword

Danger

hcodes

H302,H311,H314,H317,H335,H341,H350,H360F,H372

pcodes

P202 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Carc. 1B - Eye Dam. 1 - Muta. 2 - Repr. 1B - Skin Corr. 1C - Skin Sens. 1 - STOT RE 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

168.8 °F - closed cup

flash_point_c

76 °C - closed cup

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Styrene-assisted melt free radical grafting of glycidyl methacrylate onto polypropylene

Cartier H and Hu GH

Journal of Polymer Science Part A: Polymer Chemistry, 36(7), 1053-1063 (1998)

Mechanistic insights for block copolymer morphologies: how do worms form vesicles?

Adam Blanazs et al.

Journal of the American Chemical Society, 133(41), 16581-16587 (2011-08-19)

Amphiphilic diblock copolymers composed of two covalently linked, chemically distinct chains can be considered to be biological mimics of cell membrane-forming lipid molecules, but with typically more than an order of magnitude increase in molecular weight. These macromolecular amphiphiles are

Synthesis, characterization, and polymerization of glycidyl methacrylate derivatized dextran.

van Dijk-Wolthuis WNE, et al.

Macromolecules, 28(18), 6317-6322 (1995)

Protein-reactive nanofibrils decorated with cartilage-derived decellularized extracellular matrix for osteochondral defects.

Hye Sung Kim et al.

Biomaterials, 269, 120214-120214 (2020-08-02)

Cartilage defect is difficult to heal due to its avascular properties. Implantation of mesenchymal stem cell is one of the most promising approach for regenerating cartilage defects. Here we prepared polymeric nanofibrils decorated with cartilage-derived decellularized extracellular matrix (dECM) as

Molded? macroporous poly (glycidyl methacrylate-co-trimethylolpropane trimethacrylate) materials with fine controlled porous properties: preparation of monoliths using photoinitiated polymerization

Viklund C, et al

Chemistry of Materials, 9(2), 463-471 (1997)

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