185892
Ethyl chloroformate
97%
Sinónimos:
Chloroformic acid ethyl ester
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vapor density
3.74 (vs air)
Quality Segment
vapor pressure
3.42 psi ( 20 °C)
assay
97%
form
liquid
autoignition temp.
842 °F
refractive index
n20/D 1.395 (lit.)
bp
93 °C (lit.)
mp
−81 °C (lit.)
solubility
alcohol: miscible, benzene: miscible, chloroform: miscible, diethyl ether: miscible, water: insoluble
density
1.135 g/mL at 25 °C (lit.)
functional group
chloro
SMILES string
CCOC(Cl)=O
InChI
1S/C3H5ClO2/c1-2-6-3(4)5/h2H2,1H3
InChI key
RIFGWPKJUGCATF-UHFFFAOYSA-N
Application
- Ethyl chloroformate was used in the synthesis of nitrile oxides.
- It was used as derivatization reagent to investigate stereochemical conversion of chiral non-steroidal anti-inflammatory drugs during derivatization reaction.
- It was used to develop flexible template strategy for the generation of nanometer-scale templates via dip-pen nanolithography.
- It was used as derivatization reagent in an enantiomeric analysis of amino acids by two-dimensional gas chromatography.
- It was also used with ammonia and cyanuric chloride to convert carboxylic acids to nitriles.
Packaging
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Corr. 1B
Clase de almacenamiento
3 - Flammable liquids
wgk
WGK 1
flash_point_f
60.8 °F
flash_point_c
16 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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