Skip to Content
Merck

Key Documents

View All Documentation

ALD00002

Li-Quinoline Ligand

Synonym(s):

3,4-Dihydro-2,5-dimethyl-2H-pyrano[2,3-b]quinoline

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View

About This Item

Empirical Formula (Hill Notation):
C14H15NO
CAS Number:
151657-37-3
Molecular Weight:
213.28
NACRES:
NA.22
PubChem Substance ID:
329772508
UNSPSC Code:
12352005
MDL number:
MFCD28053559
Form:
solid
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

form

solid

Quality Segment

100

reaction suitability

reagent type: catalyst, reagent type: ligand
reaction type: C-H Activation

mp

143-147 °C

SMILES string

CC1=C2C(OC(C)CC2)=NC3=C1C=CC=C3

InChI

1S/C14H15NO/c1-9-7-8-12-10(2)11-5-3-4-6-13(11)15-14(12)16-9/h3-6,9H,7-8H2,1-2H3

InChI key

ZENOEMLZOZWVRD-UHFFFAOYSA-N

Application

Ligand can be used in the presence of Pd(TFA)2 (Aldrich 299685) to promote C-H activation of β-Aryl-α-amino acids. This product has shown to be optimal with a 2:1 ratio of Ligand:Pd Source for several examples reported by the Yu group.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

It looks like we've run into a problem, but you can still download Certificates of Analysis from our Documents section.

If you need assistance, please contact Customer Support

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library