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Merck

1.01154

di-Ammonium hydrogen citrate

for analysis EMSURE® ACS,Reag. Ph Eur

Synonym(s):

di-Ammonium hydrogen citrate, Ammonium citrate dibasic, Diammonium hydrogen citrate

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About This Item

Empirical Formula (Hill Notation):
C6H14N2O7
CAS Number:
Molecular Weight:
226.18
UNSPSC Code:
12352107
EC Index Number:
221-146-3
NACRES:
NA.21
MDL number:
Assay:
99.0-102.0% (alkalimetric)
Grade:
ACS reagent
Form:
solid
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grade

ACS reagent

Quality Segment

agency

reag. Ph. Eur.

product line

EMSURE®

assay

99.0-102.0% (alkalimetric)

form

solid

impurities

≤0.005% Insoluble matter

ign. residue

≤0.01% (as sulfate)

pH

3.3-5.3 (23 g/L in H2O)

density

1.48 g/cm3 at 20 °C

bulk density

400‑600 kg/m3

anion traces

chloride (Cl-): ≤0.0005%, oxalate (C2O42-): passes test (limit about 0.05%), phosphate (PO43-): ≤0.0005%, sulfur compounds (as SO42-): ≤0.005%

cation traces

Fe: ≤0.0005%, (heavy metals (ACS) ≤ 0.0005%)

storage temp.

2-30°C

SMILES string

[NH4]OC(=O)C(O)(CC(=O)O[NH4])CC(=O)O

InChI

1S/C6H8O7.2H3N/c7-3(8)1-6(13,5(11)12)2-4(9)10;;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);2*1H3

InChI key

YXVFQADLFFNVDS-UHFFFAOYSA-N

Application


  • An EPR and optical absorption study of VO2+ ions in di-ammonium hydrogen citrate [(NH4)2C6H6O7] single crystals.: This research examines the electronic paramagnetic resonance and optical properties of VO2+ ions in di-ammonium hydrogen citrate, which could influence analytical techniques in chemistry and materials science (Karabulut and Tufan, 2008).

Analysis Note

Assay (alkalimetric): 99.0 - 102.0 %
Insoluble matter: ≤ 0.005 %
pH-value (0.1 mol/L): 3.3 - 5.3
Chloride (Cl): ≤ 0.0005 %
Oxalate (C₂O₄): passes test (Limit about 0.05 %)
Phosphate (PO₄): ≤ 0.0005 %
Total sulfur (as SO₄): ≤ 0.005 %
Heavy metals (ACS): ≤ 0.0005 %
Fe (Iron): ≤ 0.0005 %
Residue on ignition (as sulfate): ≤ 0.01 %
Corresponds to ACS,Reag. Ph Eur

Other Notes

Replaces: AX1285-1; AX1285; AX1285-3; AX1285-20

Legal Information

EMSURE is a registered trademark of Merck KGaA, Darmstadt, Germany


pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



Certificates of Analysis (COA)

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