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751618

MorDalphos

Name: MorDalphos
Brand: ALDRICH

97%, solid

Synonym(s):

Di(1-adamantyl)-2-morpholinophenylphosphine

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About This Item

Empirical Formula (Hill Notation):

C₃₀H₄₂NOP

CAS Number:

1237588-12-3

Molecular Weight:

463.63

UNSPSC Code:

12352005

PubChem Substance ID:

329766227

NACRES:

NA.22

MDL number:

MFCD17018759

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Properties

Product Name

MorDalphos, 97%

Quality Segment

100

product line

Buchwald Ligand

assay

97%

form

solid

reaction suitability

reagent type: ligand
reaction type: Arylations, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction

mp

219-224 °C

functional group

phosphine

storage temp.

2-8°C

SMILES string

C1CN(CCO1)c2ccccc2P([C@@]34C[C@@H]5C[C@@H](C[C@@H](C5)C3)C4)[C@@]67C[C@@H]8C[C@@H](C[C@@H](C8)C6)C7

InChI

1S/C30H42NOP/c1-2-4-28(27(3-1)31-5-7-32-8-6-31)33(29-15-21-9-22(16-29)11-23(10-21)17-29)30-18-24-12-25(19-30)14-26(13-24)20-30/h1-4,21-26H,5-20H2/t21-,22+,23-,24-,25+,26-,29-,30-

InChI key

CCBRRSUORFMQCZ-BVIFAWIJSA-N

Description

Application

MorDalphos is an electronically rich, sterically hindered P,N-based ancillary ligand developed by the Stradiotto group that can be used in the Buchwald-Hartwig Amination reaction, alkyne hydroamination and monoarylation of compounds such as ammonia, hydrazine, and acetone.

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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c