375934
N-tert-Butyldimethylsilyl-N-methyltrifluoroacetamide
≥95%, with 1% tert-Butyldimethylchlorosilane
別名:
MTBSTFA+TBDMSCl, 99:1, N-メチル-N-tert-ブチルジメチルシリルトリフルオロアセトアミド, MTBSTFA＋1％ TBDMSCl, シリル化混合物VI
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この商品について
実験式（ヒル表記法）:
C9H18F3NOSi
CAS番号:
分子量:
241.33
UNSPSC Code:
12352001
PubChem Substance ID:
NACRES:
NA.22
Beilstein/REAXYS Number:
3606546
MDL number:
製品名
N-tert-ブチルジメチルシリル-N-メチルトリフルオロアセトアミド＋1％ tert-ブチルジメチルクロロシラン, ≥95%
SMILES string
CN(C(=O)C(F)(F)F)[Si](C)(C)C(C)(C)C
InChI
1S/C9H18F3NOSi/c1-8(2,3)15(5,6)13(4)7(14)9(10,11)12/h1-6H3
InChI key
QRKUHYFDBWGLHJ-UHFFFAOYSA-N
assay
≥95%
form
liquid
contains
1% TBDMSCl
functional group
amine
fluoro
storage temp.
−20°C
Quality Level
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Application
1%tert-ブチルジメチルクロロシランと共に提供されるN-tert-ブチルメチルシリル-N-メチルトリフルオロアセトアミドは、ナイトロジェンマスタードの加水分解で生じるN-tert-ブチルジメチルシリルエタノールアミンの調製に一般的に使用されます。また、N,O-ジアシルヒドロキシルアミンの選択的O-シリル化にも使用されます。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2
保管分類
3 - Flammable liquids
wgk
WGK 3
flash_point_f
113.0 °F - closed cup
flash_point_c
45 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Organometallics, 23, 2157-2161 (2004)
Tsubasa Nakajima et al.
Plant & cell physiology, 55(9), 1605-1612 (2014-06-28)
Cyanobacteria have flexible metabolic capability that enables them to adapt to various environments. To investigate their underlying metabolic regulation mechanisms, we performed an integrated analysis of metabolic flux using transcriptomic and metabolomic data of a cyanobacterium Synechocystis sp. PCC 6803
Xiaowei Wang et al.
Journal of chromatography. A, 1216(35), 6267-6273 (2009-07-31)
A sample pretreatment method for the determination of 18 chlorophenols (CPs) in aqueous samples by derivatization liquid-phase microextraction (LPME) was investigated using gas chromatography-mass spectrometry. Derivatization reagent was spiked into the extraction solvent to combine derivatization and extraction into one
R Montes et al.
Journal of chromatography. A, 1216(2), 205-210 (2008-12-17)
A fast and novel sample preparation procedure for the determination of triclosan (TCS) and methyltriclosan (MTCS) in water samples is presented. Dispersive liquid-liquid microextraction, using a ternary mixture consisting of a disperser, an extractant and N-methyl-N-(tert-butyldimethylsilyl)trifluoroacetamide (MTBSTFA) as derivatization reagent
P Canosa et al.
Journal of chromatography. A, 1072(1), 107-115 (2005-05-11)
A solid-phase microextraction (SPME) method for the determination of triclosan, methyl triclosan, 2,4-dichlorophenol and 2,3,4-trichlorophenol (considered as possible triclosan metabolites) in water samples was optimised. Analytes were first concentrated on a SPME fibre, directly exposed to the sample, and then
資料
Results of a study involving the ability few Fluka silylating reagents to form GC-MS-compatible trimethylsilylmethyl derivatives of NSAIDs
ライフサイエンス、有機合成、材料科学、クロマトグラフィー、分析など、あらゆる分野の研究に経験のあるメンバーがおります。.
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