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Merck

239305

Sodium hypochlorite solution

greener alternative

reagent grade, available chlorine 4.00-4.99 %

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Fórmula lineal:
NaClO
Número CAS:
Peso molecular:
74.44
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
231-668-3
MDL number:
Grade:
reagent grade
Form:
liquid
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grade

reagent grade

Quality Segment

agency

suitable for SM 4500 - NH3

vapor pressure

17.5 mmHg ( 20 °C)

form

liquid

composition

available chlorine, 4.00-4.99%

reaction suitability

reagent type: oxidant

greener alternative product characteristics

Safer Solvents and Auxiliaries
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

4.00-4.99% (chlorine by Na2S2O3, titration)

density

1.097 g/mL at 25 °C

greener alternative category

storage temp.

2-8°C

SMILES string

[Na+].[O-]Cl

InChI

1S/ClO.Na/c1-2;/q-1;+1

InChI key

SUKJFIGYRHOWBL-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product is considered as an environmentally benign oxidant and has been enhanced for "Safer Solvents and Auxiliaries". Click here for more information.
Sodium hypochlorite (NaOCl) is a commonly used reagent in organic synthesis for many oxidation and chlorination reactions.

Application

Sodium hypochlorite solution can be used as an oxidizing agent for the oxidation of:      
  • Primary alcohols to aldehydes or carboxylic acids and secondary alcohols to ketones.     
  • Aryl aldehydes to the corresponding acids in the presence of a phase-transfer catalyst.      
  • Ethers to esters by careful pH control (pH range of 8–9.5),

It can also be used as a reagent in the:      
  • Epoxidation of enones and polycyclic arenes.      
  • Oxidative degradation reaction      
  • N-Chlorination of primary and secondary amines
  • Enantioselective epoxidation of α, β-unsaturated ketones      
  • Asymmetric dihydroxylation of olefins in the presence of an osmium catalyst      
  • Chlorination of allylic carbons in the presence of CeCl3

Features and Benefits

  • Readily available reagent      
  • Easily handled oxidizing agent      
  • No phase-transfer catalyst is necessary for the oxidation of substrates in the pH range 10–11     
  • Simplified waste disposal and lower toxicity

Disclaimer

“The product is not intended for use as a biocide under global biocide regulations, including but not limited to US EPA′s Federal Insecticide Fungicide and Rodenticide Act, European Biocidal Products Regulation, Canada’s Pest Management Regulatory Agency, Turkey’s Biocidal Products Regulation, Korea’s Consumer Chemical Products and Biocide Safety Management Act (K-BPR) and others.”


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Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2

Clase de almacenamiento

12 - Non Combustible Liquids

flash_point_f

Not applicable

flash_point_c

Not applicable



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