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Merck

450227

Lithium hexafluorophosphate

greener alternative

battery grade, ≥99.99% trace metals basis

Synonym(s):

Lithium phosphorus fluoride

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About This Item

Linear Formula:
LiPF6
CAS Number:
21324-40-3
Molecular Weight:
151.91
NACRES:
NA.23
PubChem Substance ID:
24868544
UNSPSC Code:
12352302
EC Number:
244-334-7
MDL number:
MFCD00011096
Assay:
≥99.99% trace metals basis
Grade:
battery grade
Form:
powder

Key Documents

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Quality Level

100

grade

battery grade

assay

≥99.99% trace metals basis

form

powder

reaction suitability

core: lithium

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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impurities

≤100.0 ppm Trace Metal Analysis

mp

200 °C (dec.) (lit.)

greener alternative category

Enabling,

SMILES string

[Li+].F[P-](F)(F)(F)(F)F

InChI

1S/F6P.Li/c1-7(2,3,4,5)6;/q-1;+1

InChI key

AXPLOJNSKRXQPA-UHFFFAOYSA-N

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General description

Lithium hexafluorophosphate (LiPF₆), battery grade, ≥99.99% trace metals basis comes as a white powder with trace metal impurities < 100.0 ppm. Lithium hexafluorophosphate is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.

Application

Lithium hexafluorophosphate (LiPF₆) battery grade is designed for battery research. It can be used in the research and development of lithium-ion batteries (LIBs). Its role as a primary electrolyte salt is pivotal due to its high ionic conductivity, electrochemical stability, and compatibility with a wide range of electrode materials. It helps in the formation of a stable solid electrolyte interphase (SEI) on the anode surface, which is essential for the longevity and stability of the battery, reducing the risk of thermal runaway and enhancing the overall safety of lithium-ion batteries. LiPF₆ can be used in the development of ionic liquid electrolytes, which offer advantages such as non-flammability and wider electrochemical windows.

Features and Benefits

The product is designed with stringent parameters to fulfill the research needs in batteries. It ensures minimal interference from contaminants in trace metal analysis, providing high-purity results.
  • Exceptional Purity: ≥99.99% purity minimizes contamination from trace metals, ensuring suitability for applications sensitive to even minute impurities.
  • Consistent Performance: Ultra-high purity guarantees consistent performance across various applications, reducing variability and enhancing reliability.
  • High Purity Standard: Ideal as a standard or reagent for trace metal analysis and high-precision analytical techniques, ensuring accurate and reliable results.
  • Battery grade for use in battery applications, ensuring suitability and performance.

Other Notes

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Preparation and characterization of lithium hexafluorophosphate for lithium-ion battery electrolyte.

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Danger

Hazard Classifications

Acute Tox. 3 Oral - Skin Corr. 1A - STOT RE 1 Inhalation

target_organs

Bone,Teeth

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKCX8696
MKCW5470
MKCV5214
MKCW0783
MKCT1760

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Proc. Power Sources Conf., 37th, 231-231 (1996)
Kewei Liu et al.
ACS nano, 9(6), 6041-6049 (2015-06-06)
The two-dimensional single-layer and few-layered graphene exhibit many attractive properties such as large specific surface area and high charge carrier mobility. However, graphene sheets tend to stack together and form aggregates, which do not possess the desirable properties associated with
M D S Lekgoathi et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 153, 651-654 (2015-10-11)
The structure of LiPF6 has been probed using Raman scattering as well as pXRD and the results are compared and contrasted. The conventional Bragg angle scattering pXRD determines that dry LiPF6 crystallizes in a trigonal structure (Space Group R-3 (148))
Infrared spectroscopy studies on stability of dimethyl sulfoxide for application in a Li?air battery
Mozhzhukhina N, et al.
The Journal of Physical Chemistry C, 117(36), 18375-18380 (2013)
Shijia Zhao et al.
Nanoscale, 7(5), 1984-1993 (2014-12-30)
Hydrogenated carbon nanomaterials exhibit many advantages in both mechanical and electrochemical properties, and thus have a wide range of potential applications. However, methods to control the hydrogenation and the effect of hydrogenation on the microstructure and properties of the produced
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