8.41799
Calcium hypochlorite
for synthesis
동의어(들):
Calcium hypochlorite
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제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
Ca(OCl)2
CAS 번호:
Molecular Weight:
142.98
UNSPSC Code:
12352302
EC Index Number:
231-908-7
NACRES:
NA.22
MDL number:
Grade:
synthesis grade
grade
synthesis grade
Quality Segment
potency
850 mg/kg LD50, oral (Rat), >2000 mg/kg LD50, skin (Rabbit)
mp
100 °C
density
2.35 g/cm3 at 20 °C
storage temp.
15-25°C
SMILES string
[Ca+2].Cl[O-].Cl[O-]
InChI
1S/Ca.2ClO/c;2*1-2/q+2;2*-1
InChI key
ZKQDCIXGCQPQNV-UHFFFAOYSA-N
General description
Calcium hypochlorite [Ca(OCl)2] is a stable oxidizing agent used for the conversion of ethers to esters; thioethers to sulfoxides; aldehydes to acids and alkenes to chlorohydrins. It is also used in the C-C bond cleavage and chlorination reactions.
Application
Calcium hypochlorite can be used as an oxidative agent:
- In the epoxidation of various alkene derivatives.
- To synthesize α-arylamino-α′-chloropropan-2-ones from various trifluoroacetyl-protected N-(2-chloroallyl)anilines via oxidative hydrolysis.
- To convert 1o & 2o alcohols, α-hydroxyamides, and α-hydroxyesters to their corresponding aldehydes, ketones, α-ketoamides, and α-ketoesters in the presence of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) as a catalyst.
- To prepare dihydrotriazolediones and bis-dihydrotriazolediones by oxidation of urazoles and bis-urazoles.
Analysis Note
Assay (iodometric): 67.0 - 75.0 %
Identity: passes test
Identity: passes test
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Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1B
supp_hazards
hcodes
저장 등급
5.1B - Oxidizing hazardous materials
시험 성적서(COA)
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