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Merck

716731

Dimethyl sulfoxide-d6

"Special HOH", ≥99.9 atom % D

동의어(들):

(Methyl sulfoxide)-d6, DMSO-d6, Hexadeuterodimethyl sulfoxide

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제품정보 (DICE 배송 시 비용 별도)

Linear Formula:
(CD3)2SO
CAS 번호:
Molecular Weight:
84.17
UNSPSC Code:
12142201
NACRES:
NA.21
PubChem Substance ID:
EC Number:
218-617-0
Beilstein/REAXYS Number:
1237248
MDL number:
Isotopic purity:
≥99.9 atom % D
Assay:
≥99% (CP)
Mass shift:
M+6
Form:
liquid
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vapor pressure

0.42 mmHg ( 20 °C)

Quality Segment

isotopic purity

≥99.9 atom % D

assay

≥99% (CP)

form

liquid

autoignition temp.

573 °F

expl. lim.

42 %

technique(s)

NMR: suitable

refractive index

n20/D 1.476 (lit.)

bp

189 °C (lit.)

mp

20.2 °C (lit.)

density

1.190 g/mL at 25 °C (lit.)

mass shift

M+6

SMILES string

[2H]C([2H])([2H])S(=O)C([2H])([2H])[2H]

InChI

1S/C2H6OS/c1-4(2)3/h1-2H3/i1D3,2D3

InChI key

IAZDPXIOMUYVGZ-WFGJKAKNSA-N

General description

Dimethyl sulfoxide-d6 (DMSO-d6) is a deuterated NMR solvent. It undergoes photodissociation to generate CD3 radical photoproducts, which have been analyzed by infrared diode laserabsorption spectroscopy. Dissociation dynamics of DMSO-d6 at 193nm was examined using photo fragment translational spectroscopy method.

Application

Dimethyl sulfoxide-d6 may be used as an NMR solvent for 1H and 13C NMR experiments.

Other Notes

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저장 등급

10 - Combustible liquids

wgk

WGK 1

flash_point_f

190.4 °F

flash_point_c

88 °C



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관련 콘텐츠


Solution forms of an antitumor cyclic hexapeptide, RA-VII in dimethyl sulfoxide-d6 from nuclear magnetic resonance studies.
Itokawa H, et al.
Chemical & Pharmaceutical Bulletin, 40(4), 1050-1052 (1992)
Unraveling the dissociation of dimethyl sulfoxide following absorption at 193 nm.
Blank DA, et al.
J. Chem. Phys. , 106(2), 539-550 (1997)
Diode laser measurements of CD3 quantum yields and internal energy for the dissociation of dimethyl sulfoxide-d6.
Rudolph RN, et al.
J. Chem. Phys. , 106(4), 1346-1352 (1997)