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109164 Hanus solution

for determination of iodine number c(IBr) = 0.1 mol/l Titripur®

Hanus solution MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.

Synonyms: Iodine solution acc. to Hanus

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109164
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      1.09164.1003
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          Description
          Catalogue Number109164
          SynonymsIodine solution acc. to Hanus
          References
          Product Information
          HS Code3822 19 90
          Quality LevelMQ200
          Applications
          Biological Information
          Physicochemical Information
          Density1.06 g/cm3 (20 °C)
          Flash point40 °C
          pH value<1 (H₂O, 20 °C)
          Dimensions
          Materials Information
          Toxicological Information
          Safety Information according to GHS
          Hazard Pictogram(s) Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Statement(s)H226: Flammable liquid and vapour.
          H314: Causes severe skin burns and eye damage.
          Precautionary Statement(s)P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
          P233: Keep container tightly closed.
          P240: Ground and bond container and receiving equipment.
          P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
          P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
          P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
          Signal WordDanger
          Storage class3 Flammable liquids
          WGKWGK 2 obviously hazardous to water
          Disposal12
          Inorganic acids and anhydrides thereof should first be diluted or hydrolyzed by stirring carefully into ice water and then neutralized (protective gloves, fume cupboard!) with sodium hydroxide solution (Cat. No. 105587). Before filling into container D, check the pH with pH universal indicator strips (Cat. No. 109535). Fuming sulfuric acid should be carefully stirred dropwise into 40 % sulfuric acid (Cat. No. 109286). Ensure that plenty of ice is available for cooling! When sufficiently cool, treat the highly concentrated sulfuric acid as described above. Analogous to this procedure, other anhydrides can be converted into their corresponding acids. Acid gases (e.g. hydrogen halide, chlorine, phosgene, sulfur dioxide) can be introduced into dilute sodium hydroxide solution and after neutralization disposed of in container D.
          Safety Information
          Categories of dangerflammable, corrosive
          Product Usage Statements
          Storage and Shipping Information
          StorageStore at +15°C to +25°C.
          Packaging Information
          Transport Information
          Declaration (railroad and road) ADR, RIDUN 2789 , 8 (3), II
          Declaration (transport by air) IATA-DGRUN 2789 , 8 (3), II
          Declaration (transport by sea) IMDG-CodeUN 2789 , 8 (3), II, Segregation Group: 1 (Acids)
          Supplemental Information
          Specifications
          Formliquid
          Amount-of-substance concentration0.0994 - 0.1006 mol/l
          Measurement uncertainty+/- 0.0004
          TraceabilityNIST SRM
          The stated batch and specification values for the amount of substance concentration are valid at the time of bottling.
          The amount-of-substance concentration of this volumetric solution is analyzed by our quality control laboratory of Merck KGaA, Darmstadt, Germany according to DIN EN ISO/IEC 17025.
          The concentration is determined by volumetric titration and refers to 20°C.
          The amount-of-substance concentration of this volumetric solution is determined with standardized sodium thiosulfate solution (article number 1.09147). The sodium thiosulfate solution is standardized and traceable to a primary standard reference material (SRM) from the National Institute of Standards and Technology, Gaithersburg, USA (NIST SRM 136 potassium dichromate) by means of volumetric standard potassium iodate (article number 1.02404), certified reference material according to ISO 17034, analyzed by our accredited calibration laboratory of Merck KGaA, Darmstadt, Germany according to DIN EN ISO/IEC 17025. The uncertainty is expressed as expanded measurement uncertainty with a coverage factor k=2 covering a confidence level of 95%.
          Note: The concentration of this volumetric solution decreases over time, due to its chemical properties. If high accuracy is expected, the titer, being a corrective factor that compensates for this effect as well as variations of equipment, personal handling, temperature and other laboratory conditions, must be determined directly after opening a new bottle and should be verified at regular intervals.
          Global Trade Item Number
          Catalogue Number GTIN
          1.09164.1000 04022536111483
          1.09164.1003 04054839999376

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