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Merck

160512

Fmoc chloride

97%, for peptide synthesis

Synonym(s):

9-Fluorenylmethoxycarbonyl chloride, 9-Fluorenylmethyl chloroformate, Fmoc-Cl

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About This Item

Empirical Formula (Hill Notation):
C15H11ClO2
CAS Number:
28920-43-6
Molecular Weight:
258.70
NACRES:
NA.22
PubChem Substance ID:
24849875
UNSPSC Code:
12352108
EC Number:
249-313-6
MDL number:
MFCD00001138
Beilstein/REAXYS Number:
2279177

Product Name

Fmoc chloride, 97%

form

solid

SMILES string

ClC(=O)OCC1c2ccccc2-c3ccccc13

InChI key

IRXSLJNXXZKURP-UHFFFAOYSA-N

InChI

1S/C15H11ClO2/c16-15(17)18-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14H,9H2

assay

97%

mp

62-64 °C (lit.)

application(s)

peptide synthesis

functional group

Fmoc
chloro

storage temp.

2-8°C

Quality Level

200

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Related Categories

Application

Amino acid derivatizing agent for HPLC analysis. N-protecting reagent for peptide and oligonucleotide syntheses.
Reagent for amino group protection recently used in the synthesis of a bicyclic proline analog.
Reagent for derivatizing amino acids for HPLC amino acid analysis and for preparing N-Fmoc amino acids for solid-phase peptide synthesis.

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

supp_hazards

EUH029

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
0000504926
0000504925
0000504925
0000504926
WXBF6776V

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Helvetica Chimica Acta, 75, 1111-1111 (1992)
Journal of the Chemical Society. Chemical Communications, 369-369 (1993)
Brett H Pogostin et al.
Molecules (Basel, Switzerland), 24(3) (2019-01-27)
Determining the pKa of key functional groups is critical to understanding the pH-dependent behavior of biological proteins and peptide-based biomaterials. Traditionally, ¹H NMR spectroscopy has been used to determine the pKa of amino acids; however, for larger molecules and aggregating
Jae Hyun Kim et al.
Nanomaterials (Basel, Switzerland), 11(1) (2020-12-31)
Here, we report a post-synthesis functionalization of the shell of Au nanoclusters (NCs) synthesized using glutathione as a thiolate ligand. The as-synthesized Au NCs are subjected to the post-synthesis functionalization via amidic coupling of dopamine on the cluster shell to
Synthesis, 3122-3122 (2006)
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