Millipore Sigma Vibrant Logo
Attention: We have moved. Merck Millipore products are no longer available for purchase on MerckMillipore.com.Learn More

822339 Phosphoryl chloride

822339
Purchase on Sigma-Aldrich

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaChemical FormulaMolar Mass
10025-87-3233-046-7Cl₃OPPOCl₃153.33 g/mol

Products

Catalogue NumberPackaging Qty/Pack
8.22339.1000 Glass btl. pl.coat. 1 l
Description
Catalogue Number822339
SynonymsPhosphorus oxide trichloride, Phosphorus oxychloride
DescriptionPhosphoryl chloride
References
Product Information
CAS number10025-87-3
EC index number015-009-00-5
EC number233-046-7
Hill FormulaCl₃OP
Chemical formulaPOCl₃
Molar Mass153.33 g/mol
HS Code2812 12 00
Quality LevelMQ200
Applications
ApplicationPhosphoryl chloride for synthesis. CAS 10025-87-3, EC Number 233-046-7, chemical formula POCl₃.
Biological Information
Physicochemical Information
Boiling point105.3 °C (1013 hPa)
Density1.645 g/cm3 (25 °C) DIN 51757
Melting Point1.18 °C
pH value1 (H₂O, 20 °C)
Vapor pressure37 hPa (20 °C)
Dimensions
Materials Information
Toxicological Information
LD 50 oralLD50 Rat 36 mg/kg
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H330: Fatal if inhaled.
H372: Causes damage to organs through prolonged or repeated exposure if inhaled.
EUH014: Reacts violently with water.
EUH029: Contact with water liberates toxic gas.
Precautionary Statement(s)P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P301 + P312: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get medical advice/ attention if you feel unwell.
Signal WordDanger
RTECSTH4897000
Storage class6.1B Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 1 slightly hazardous to water
Disposal24
Liquid inorganic halides and hydrolysis-sensitive reagents can be carefully stirred dropwise into ice-cool 10% sodium hydroxide solution (Cat. No. 105587) (caution: caustic gases!); container D or E.
Safety Information
Categories of dangervery toxic, corrosive
Product Usage Statements
Storage and Shipping Information
StorageStore below +30°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 1810 , 6.1 (8), I
Declaration (transport by air) IATA-DGRUN 1810 , 6.1 (8),
Declaration (transport by sea) IMDG-CodeUN 1810 , 6.1 (8), I, Segregation Group: 1 (Acids)
Supplemental Information
Specifications
Color according to color reference solution Ph.Eur.colorless liquid
Assay (argentometric)≥ 99.0 %
Density (d 20 °C/ 4 °C)1.673 - 1.677
Identity (IR)passes test
Global Trade Item Number
Catalogue Number GTIN
8.22339.1000 04022536489766

Documentation

Phosphoryl chloride SDS

Title

Safety Data Sheet (SDS) 

Phosphoryl chloride Certificates of Analysis

Product Number PackagingLot Number
8.22339.1000 Glass btl. pl.coat.

Related Products & Applications

Categories

Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Reagents for Nucleotide Synthesis
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Organoelement Compounds > Phosphorous Compounds
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Organoelement Compounds > Phosphorous Compounds
Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Organoelement Compounds > Phosphorous Compounds
Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Reagents for Nucleotide Synthesis