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Merck

544841

Cerium oxide

greener alternative

nanopowder, <25 nm particle size (BET)

Sinónimos:

Cerium dioxide, Cerium(IV) oxide, Ceric oxide, Ceric oxide, ceria

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Acerca de este artículo

Fórmula lineal:
CeO2
Número CAS:
Peso molecular:
172.11
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
26111700
EC Number:
215-150-4
MDL number:
eCl@ss:
38160411
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Nombre del producto

Cerium(IV) oxide, nanopowder, <25 nm particle size (BET)

InChI key

CETPSERCERDGAM-UHFFFAOYSA-N

InChI

1S/Ce.2O

SMILES string

O=[Ce]=O

form

nanopowder

reaction suitability

reagent type: catalyst
core: cerium

greener alternative product characteristics

Design for Energy Efficiency
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sustainability

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particle size

<25 nm (BET)

density

7.13 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

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Quality Level

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General description

Cerium(IV)oxide (CeO₂), also known as ceric oxide, ceria, or cerium dioxide, is an oxide of the rare-earth metal cerium. It appears as a white to yellow nanopowder with a particle size of less than 25 nm (BET), exhibiting high surface area and reactivity. It is used in various applications, including catalysis, electrochemical applications, and in glass and ceramics. CeO₂ is widely employed in catalytic converters for automotive applications, where it aids in the reduction of harmful emissions. Additionally, it is used in the production of advanced ceramics, glass polishing, and as a catalyst in various chemical reactions. Its unique properties also make it valuable in solid oxide fuel cells and as a UV filter in sunscreens.

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Application

CeO2nanopowder is utilized in solid oxide fuel cells (SOFCs) due to its ionicconductivity and stability at high temperatures. It is also used in batteriesand supercapacitors to improve performance. Additionally, CeO2 is used as a polishing powder in the glass andsemiconductor industries. Its fine particle size and hardness make it effectivefor achieving high surface finishes on optical components.
The additon of CeO2 to CuO/TiO2 increases specific surface area and inhibits sintering and pore size growth at high temperatures.

Legal Information

Product of Engi-Mat Co.

Clase de almacenamiento

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Gao Li et al.
Chemical communications (Cambridge, England), 48(98), 12005-12007 (2012-11-07)
The Au(25)(SR)(18)/CeO(2) nanocluster catalyst showed high activity in the homocoupling of aryl iodides (e.g. up to 99.8% yield with iodobenzene) and excellent recyclability.
Dengsong Zhang et al.
Nanoscale, 5(3), 1127-1136 (2013-01-04)
The MnO(x) and CeO(x) were in situ supported on carbon nanotubes (CNTs) by a poly(sodium 4-styrenesulfonate) assisted reflux route for the low-temperature selective catalytic reduction (SCR) of NO with NH(3). X-Ray diffraction (XRD), transmission electron microscopy (TEM), high-resolution TEM (HRTEM)
Vishal Shah et al.
PloS one, 7(10), e47827-e47827 (2012-10-31)
Cerium oxide nanoparticles have found numerous applications in the biomedical industry due to their strong antioxidant properties. In the current study, we report the influence of nine different physical and chemical parameters: pH, aeration and, concentrations of MgSO(4), CaCl(2), KCl
Cecilia Mondelli et al.
Chimia, 66(9), 694-698 (2012-12-06)
The heterogeneously catalyzed gas-phase oxidation of HCl to Cl(2) offers an energy-efficient and eco- friendly route to recover chlorine from HCl-containing byproduct streams in the chemical industry. This process has attracted renewed interest in the last decade due to an
Hailong Li et al.
Journal of hazardous materials, 243, 117-123 (2012-11-08)
MnO(x)-CeO(2) mixed-oxide supported on TiO(2) (Mn-Ce/Ti) was synthesized by an ultrasound-assisted impregnation method and employed to oxidize elemental mercury (Hg(0)) at 200°C in simulated coal combustion flue gas. Over 90% of Hg(0) oxidation was achieved on the Mn-Ce/Ti catalyst at

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