298190
Cerium(III) chloride
AnhydroBeads™, −10 mesh, 99.9%
Synonym(s):
Cerium trichloride, Cerous chloride
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About This Item
Empirical Formula (Hill Notation):
CeCl3
CAS Number:
Molecular Weight:
246.48
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
232-227-8
MDL number:
Assay:
99.9%
Grade:
synthesis grade
grade
synthesis grade
product line
AnhydroBeads™
assay
99.9%
reaction suitability
core: cerium, reagent type: catalyst
impurities
≤1500.0 ppm Trace Rare Earth Analysis
particle size
−10 mesh
mp
848 °C (lit.)
density
3.97 g/mL at 25 °C (lit.)
SMILES string
Cl[Ce](Cl)Cl
InChI
1S/Ce.3ClH/h;3*1H/q+3;;;/p-3
InChI key
VYLVYHXQOHJDJL-UHFFFAOYSA-K
Application
When added to nitrile aldol reactions, diastereoselectivity is enhanced, providing high yields of β-hydroxynitriles.
Legal Information
AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC
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Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1C
Storage Class
8B - Non-combustible corrosive hazardous materials
wgk
WGK 2
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Na Li et al.
Environmental toxicology, 28(6), 349-358 (2011-06-10)
To investigate the molecular mechanism of inflammatory response in the mouse liver caused by exposure to CeCl₃, we measured the liver indices, and cerium content, evaluated the liver histopathological section, detected serum biochemical parameters of liver function, and the immunoglobulin
Yanfang Wu et al.
Chemosphere, 74(9), 1260-1265 (2008-12-17)
Using both histochemical and cytochemical methods, we investigated the effects of copper (Cu) on the production of hydrogen peroxide (H2O2) and superoxide anion (O2(.-)) in the leaves of the moss Plagiomnium cuspidatum. Cu treatment significantly increased the contents of total
Xiaoming Tao et al.
Organic letters, 15(1), 72-75 (2012-12-25)
Dynamic kinetic resolution of various α-amido-β-keto phosphonates via asymmetric hydrogenation proceeded efficiently to give the corresponding β-hydroxy-α-amido phosphonates in high diastereo- and enantioselectivities (up to 99:1 syn/anti, 99.8% ee). The addition of catalytic amounts of CeCl(3)·7H(2)O is necessary to achieve