33820
Dibenzyl sulfide
≥95.0% (HPLC)
Synonym(s):
Benzyl sulfide
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About This Item
Linear Formula:
(C6H5CH2)2S
CAS Number:
Molecular Weight:
214.33
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-703-6
Beilstein/REAXYS Number:
1911157
MDL number:
Product Name
Dibenzyl sulfide, ≥95.0% (HPLC)
InChI key
LUFPJJNWMYZRQE-UHFFFAOYSA-N
InChI
1S/C14H14S/c1-3-7-13(8-4-1)11-15-12-14-9-5-2-6-10-14/h1-10H,11-12H2
SMILES string
C(SCc1ccccc1)c2ccccc2
assay
≥95.0% (HPLC)
form
solid
mp
44-47 °C (lit.)
functional group
phenyl
thioether
Quality Level
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General description
Sulfur K-edge XANES spectra of dibenzyl sulfide has been measured. Adsorption modes of dibenzyl disulphide on bare and iron-coated silver in 0.5M HCl was studied by surface-enhanced Raman scattering (SERS) spectroscopy. Dibenzyl sulfide undergoes oxidation to dibenzyl sulfoxide by SiO2-HNO3/KBr.
Storage Class
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Robert Beck et al.
Dalton transactions (Cambridge, England : 2003), (37)(37), 4981-4983 (2008-09-20)
C-H activation through the coordination of a benzyl sulfide anchoring group with a C-S bond cleavage at a Co(v) center constitutes a regiospecific access to four- and five-membered metallacycles under mild conditions.
Chemo and homoselective catalytic oxidation of sulfides to sulfoxides with supported nitric acid on silica gel and poly vinyl pyrrolidone (PVP) catalyzed by KBr and/or NaBr.
Zolfigol MA, et al.
Catalysis Communications, 9(8), 1739-1744 (2008)
Eun Kyoung Ryu et al.
Bioorganic & medicinal chemistry, 12(5), 859-864 (2004-02-26)
Benzyl 4-halobenzyl and ally benzyl disulfide were synthesized as diallyl disulfide analogues and their tumor growth inhibitory effects on the cancer cells (SNU C5 and MCF-7) were comparable to that of diallyl disulfide, indicating that the disulfide functional group was
Vered Heleg-Shabtai et al.
Advances in experimental medicine and biology, 733, 53-61 (2011-11-22)
The improvements in Raman instrumentation have led to the development of -portable, simple to operate, Raman instruments that can be used for on-site analysis of substances relevant for homeland security purposes such as chemical and biological warfare and explosives materials.Raman
A SERS Study on Adsorption of Dibenzyl Disulfide, Sulfide, and Sulfoxide on an Iron-Deposited Silver Electrode in a Hydrochloric Acid Solution.
Ohno N, et al.
Journal of the Electrochemical Society, 140(9), 2512-2519 (1993)
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