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Merck

672068

Vinylphosphonic acid

≥90% (T)

Synonym(s):

Ethenephosphonic acid, Ethylenephosphonic acid, P-Ethenylphosphonic acid

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About This Item

Linear Formula:
CH2=CHP(O)(OH)2
CAS Number:
1746-03-8
Molecular Weight:
108.03
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
329760454
EC Number:
217-123-2
Beilstein/REAXYS Number:
1741622
MDL number:
MFCD00043866
Assay:
≥90% (T)

Key Documents

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Product Name

Vinylphosphonic acid, ≥90% (T)

InChI

1S/C2H5O3P/c1-2-6(3,4)5/h2H,1H2,(H2,3,4,5)

InChI key

ZTWTYVWXUKTLCP-UHFFFAOYSA-N

SMILES string

OP(O)(=O)C=C

assay

≥90% (T)

impurities

≤7.0% water

mp

36 °C (Lit. dry VPA) (lit.)

density

1.37 g/mL at 20 °C (lit.)

Quality Level

100

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Application

Vinylphosphonic acid (VPA) can be used as a monomer unit for the synthesis of poly(vinylphosphonic acid) via free radical polymerization. It is also used to develop copolymers of VPA with acrylonitrile, N-isopropylacrylamide, styrene, vinylpyrrolidone, and acrylic and methacrylic acid. These copolymers find potential application in hydrogels, drug delivery, biomimetic mineralization, and polymer electrolyte membranes in fuel cells.
It can also be used as an organic building block to prepare (E)-styryl phosphonic acid derivatives by reacting with various aryl halides via Pd-catalyzed Heck coupling reaction.

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H290,H314

Hazard Classifications

Met. Corr. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

467.6 °F

flash_point_c

242 °C

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
SDBB0276
STBB3728V
STBC6081V
STBB3728
S65968

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Noh-Seok Kwak et al.
Journal of hazardous materials, 203-204, 213-220 (2012-01-03)
Poly(vinylphosphonic acid-co-methacrylic acid) microbeads were synthesized by suspension polymerization, and their indium adsorption properties were investigated. The obtained microbeads were characterized by Fourier transform infrared (FT-IR) spectroscopy and scanning electron microscopy (SEM). The microbeads were wrinkled spheres, irrespective of the
James D Kretlow et al.
Biomacromolecules, 11(3), 797-805 (2010-02-04)
Stimulus responsive materials hold great promise in biological applications as they can react to changes in physiological stimuli to produce a desired effect. Stimulus responsive macromers designed to respond to temperature changes at or around 37 degrees C and the
Richard D Bertram et al.
Biochemistry, 41(24), 7725-7731 (2002-06-12)
During the past 5 years a great deal of structural and biochemical information has given us a detailed insight into the molecular mechanism of action of the PcrA DNA helicase and challenged previous notions about the molecular mechanism of action
Synthesis, microstructure, and acidity of poly (vinylphosphonic acid)
Bingol B, et al.
Macromolecular Rapid Communications, 27(20), 1719-1724 (2006)
Young Kyung Kim et al.
Biomaterials, 31(25), 6618-6627 (2010-07-14)
The complex morphologies of mineralised collagen fibrils are regulated through interactions between the collagen matrix and non-collagenous extracellular proteins. In the present study, polyvinylphosphonic acid, a biomimetic analogue of matrix phosphoproteins, was synthesised and confirmed with FTIR and NMR. Biomimetic
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