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Merck

104876

Trichlorovinylsilane

97%

Synonym(s):

(Trichlorosilyl)ethylene, Vinyltrichlorosilane

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About This Item

Linear Formula:
H2C=CHSiCl3
CAS Number:
75-94-5
Molecular Weight:
161.49
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
24846680
EC Number:
200-917-8
Beilstein/REAXYS Number:
1743440
MDL number:
MFCD00000482

Key Documents

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Product Name

Trichlorovinylsilane, 97%

InChI key

GQIUQDDJKHLHTB-UHFFFAOYSA-N

InChI

1S/C2H3Cl3Si/c1-2-6(3,4)5/h2H,1H2

SMILES string

Cl[Si](Cl)(Cl)C=C

vapor density

>1 (vs air)

vapor pressure

60 mmHg ( 23 °C)

assay

97%

refractive index

n20/D 1.436 (lit.)

bp

90 °C (lit.)

mp

−95 °C (lit.)

density

1.27 g/mL at 25 °C (lit.)

storage temp.

2-8°C

Quality Level

100

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Application

A study reports the possible use of this silane for treating Pluronic F127, chitosan for better attachment and proliferation of endothelial cells on biomaterials. Trichlorovinylsilane may be used to prepare epoxy terminated carbosiloxane.

General description

Trichlorovinylsilane may react with lithium-tert-butyl, and 1,3-enynes to yield isomeric silacyclobutanes and silacyclobutenes respectively.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

50.0 °F - closed cup

flash_point_c

10 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
04301KJ
08501KD
04029LC
19929JB
17804TI

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Micropatterning of proteins and mammalian cells on biomaterials.
Faseb Journal, 18(3), 525-527 (2004)
Xiangming Wu et al.
Colloids and surfaces. B, Biointerfaces, 130, 69-76 (2015-04-25)
Earlier work provided direction for development of responsive drug delivery systems based on modulation of the structure, amphiphilicity, and surface density of bioactive peptides entrapped within pendant polyethylene oxide (PEO) brush layers. In this work, we describe the sequential and
Synthesis, characterization of an epoxy?terminated carbosiloxane and its application as a modifier in epoxy systems.
Polym. Eng. Sci., 52(4), 868-874 (2012)
John D DeSain et al.
Physical chemistry chemical physics : PCCP, 8(19), 2240-2248 (2006-05-12)
The absolute gas phase ultraviolet absorption spectra of trichlorovinylsilane and allyltrichlorosilane have been measured from 191 to 220 nm. Over this region the absorption spectra of both species are broad and relatively featureless, and their cross sections increase with decreasing
Dariusz Brząkalski et al.
Polymers, 12(10) (2020-10-08)
In this work, polyethylene (PE) composites were prepared with a series of completely condensed silsesquioxanes (SSQ), as well as with open-cage hepta(isobutyl)trisilanol silsesquioxane. The effect of the additives on the thermal, mechanical, rheological, and crystalline properties of the composites obtained
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