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201138

Ammonium hexafluorophosphate

≥95%

Synonym(s):

Ammonium hexafluophosphate, Ammonium hexafluorophosphate V, Ammonium phosphorus hexafluoride, Ammoniumhexafluorophosphate

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About This Item

Linear Formula:
NH4PF6
CAS Number:
16941-11-0
Molecular Weight:
163.00
PubChem Substance ID:
24851996
eCl@ss:
38070413
UNSPSC Code:
12352302
NACRES:
NA.22
EC Number:
241-009-1
MDL number:
MFCD00064642
Assay:
≥95%
Concentration:
≤100%
Form:
solid
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Quality Level

100

assay

≥95%

form

solid

concentration

≤100%

solubility

water: soluble ca.50 g/L

density

2.18 g/mL at 25 °C (lit.)

SMILES string

[H][N+]([H])([H])[H].F[P-](F)(F)(F)(F)F

InChI

1S/F6P.H3N/c1-7(2,3,4,5)6;/h;1H3/q-1;/p+1

InChI key

NIZXKAYXSNUDOU-UHFFFAOYSA-O

Application

Ammonium hexafluorophosphate (NH4PF6) can be used as a precursor for the preparation of:
  • Metal complexes, particularly iridium and rhodium complexes.       
  • Flame retardant cellulose-based materials.       
  • Cyclic amidinium and iminium ammonium hexafluorophosphate salts.        
  • The polymer-supported iridium isomerization catalyst for the selective trans isomerization of aryl allylic derivatives.

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pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
0000532185
0000540385
0000532185
0000540385
0000503019

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Preparations of iridium complexes containing phenanthroline ancillary ligands and electrical properties of cationic iridium-based light-emitting electrochemical cells
Park S, et al.
Surface and Interface Analysis : SIA, 44(11-12), 1479-1482 (2012)
A polymer-supported iridium catalyst for the stereoselective isomerisation of double bonds
Baxendale IR, et al.
Synlett, 2002(03), 0516-0518 (2002)
Homogeneous catalytic system for photoinduced hydrogen production utilizing iridium and rhodium complexes.
Cline, Eric D et al.
Inorganic Chemistry, 47(22), 10378-10388 (2008)
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