208361
Silver tetrafluoroborate
98%
Synonym(s):
Silver borofluoride
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About This Item
Linear Formula:
AgBF4
CAS Number:
Molecular Weight:
194.67
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
237-956-5
MDL number:
Product Name
Silver tetrafluoroborate, 98%
InChI key
CCAVYRRHZLAMDJ-UHFFFAOYSA-N
InChI
1S/Ag.BF4/c;2-1(3,4)5/q+1;-1
SMILES string
[Ag+].F[B-](F)(F)F
assay
98%
reaction suitability
core: silver
reagent type: catalyst
mp
70-73 °C (lit.)
Quality Level
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Application
Displaces chloride from precious metal complexes used in the oxidation of alcohols by persulfate.
Provides a silver-ion template for improved macrolatamization of a linear dipeptide.
General description
Silver tetrafluoroborate (AgBF4) is used as a Lewis acid in organic synthesis. It is known to have a high affinity towards organic halides. It is employed in organic reactions like activation of acyl chlorides, nucleophilic substitution, rearrangement, cycloaddition, cyclization, ring expansion and oxidation.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Silver tetrafluoroborate
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2005)
Synlett, 1901-1901 (2007)
Silver tetrafluoroborate
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2005)
J. Mol. Catal., 79, 85-85 (1993)
Kende, A. S.; Huang, H.
Tetrahedron Letters, 38, 3353-3353 (1997)
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