232599
Ethyl methoxyacetate
97%
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About This Item
Linear Formula:
CH3OCH2COOC2H5
CAS Number:
Molecular Weight:
118.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
223-521-7
Beilstein/REAXYS Number:
1744761
MDL number:
Assay:
97%
Form:
liquid
Quality Level
assay
97%
form
liquid
refractive index
n20/D 1.401 (lit.)
bp
44-45.5 °C/9 mmHg (lit.)
density
1.007 g/mL at 25 °C (lit.)
functional group
ester, ether
SMILES string
CCOC(=O)COC
InChI
1S/C5H10O3/c1-3-8-5(6)4-7-2/h3-4H2,1-2H3
InChI key
JLEKJZUYWFJPMB-UHFFFAOYSA-N
Application
Ethyl methoxyacetate was used:
- as acyl donor during the preparation of enantiomers of several phenylethylamines
- as acylation reagent for the aminolysis of 1-phenylethanamine
- in an industrial, lipase-catalysed kinetic resolution of primary amine
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Lourdes Muñoz et al.
Organic & biomolecular chemistry, 9(23), 8171-8177 (2011-10-06)
Both enantiomers of several phenylethylamines, structurally related to amphetamine, have been prepared in good yields and excellent enantiomeric purity by enzymatic kinetic resolution using CAL-B and ethyl methoxyacetate as the acyl donor. In the case of the 4-hydroxyderivative of amphetamine
Ulf Hanefeld
Organic & biomolecular chemistry, 1(14), 2405-2415 (2003-09-06)
Commonly, hydrolase-catalysed reactions are used for kinetic resolutions of alcohols, amines and acids. Only a few applications in total syntheses have been described. Most of these examples are for the synthesis of amides and peptides. Here, the synthesis of all
C Saito et al.
Biotechnic & histochemistry : official publication of the Biological Stain Commission, 74(1), 40-48 (1999-04-06)
An in situ hybridization procedure resulting in both high resolution and sensitivity was established by using the removable methyl methacrylate resin, Technovit 9100. Young bicellular pollen of tobacco (Nicotiana tabacum L. SR-1) was embedded in Technovit 9100 resin and sectioned.