257478
2,2,3,3,3-Pentafluoro-1-propanol
97%
Synonym(s):
PFPOH
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About This Item
Linear Formula:
CF3CF2CH2OH
CAS Number:
Molecular Weight:
150.05
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
207-012-7
Beilstein/REAXYS Number:
1743133
MDL number:
Assay:
97%
Form:
liquid
InChI key
PSQZJKGXDGNDFP-UHFFFAOYSA-N
InChI
1S/C3H3F5O/c4-2(5,1-9)3(6,7)8/h9H,1H2
SMILES string
OCC(F)(F)C(F)(F)F
assay
97%
form
liquid
refractive index
n20/D 1.288 (lit.)
bp
80 °C/748 mmHg (lit.)
density
1.505 g/mL at 25 °C (lit.)
functional group
fluoro, hydroxyl
Quality Level
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General description
2,2,3,3,3-Pentafluoro-1-propanol is an alternative cleaning agent for chlorofluorocarbon.
Application
2,2,3,3,3-Pentafluoro-1-propanol has been used:
- as derivatization reagent in detection of unlabeled and 15N2 -labeled L-tryptophan, L-kynurenine, serotonin and quinolinic acid in human and rat plasma by GC-MS
- as derivatization reagent in simultaneous analysis of cocaine, cocaethylene and their possible metabolic and pyrolytic products in blood, urine and muscle by GC-MS
- preparation of trifluoromethyl ynamines which, in turn, converted aldehydes to α-trifluoromethyl-α,β-unsaturated amides
- to generate fluorinated α-keto ethers with alkenes and has wide applications in the expanding fluorous research area
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - STOT RE 2 Inhalation
target_organs
Liver
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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M Usami et al.
Kokuritsu Iyakuhin Shokuhin Eisei Kenkyujo hokoku = Bulletin of National Institute of Health Sciences, (118)(118), 45-49 (2001-09-06)
Teratogenicity of 2,2,3,3,3-pentafluoro-1-propanol (5FP), an alternative cleaning agent for chlorofluorocarbon, was examined in rats. 5FP was diluted with sesame oil and given to pregnant rats (Crj: Wistar) by gavage once a day from day 7 to 17 of pregnancy at
Mitsue Sano et al.
Journal of mass spectrometry : JMS, 49(2), 128-135 (2014-03-29)
A method for the detection of unlabeled and (15)N2 -labeled L-tryptophan (L-Trp), L-kynurenine (L-Kyn), serotonin (5-HT) and quinolinic acid (QA) in human and rat plasma by GC/MS is described. Labeled and unlabeled versions of these four products were analyzed as
Ishihara, T.; et al.
Tetrahedron, 62, 3783-3783 (2006)
Sudha Manandhar et al.
The Journal of organic chemistry, 67(18), 6415-6420 (2002-08-31)
Interactions of various fluorinated and nonfluorinated alcohols with trans-stilbene in the presence of electrophilic reagents were studied. Under neat conditions, reactions of trans-stilbene (1) with fluorinated alcohols, R(f)OH (R(f) = CF3CH2-, CFH2CH2-, CF3CF2CH2-, CF2H(CF2)3CH2-, (CF3)2CH-, (CF3)3C- (2a-f) in the presence
Simultaneous analyses of cocaine, cocaethylene, and their possible metabolic and pyrolytic products.
Patrick S Cardona et al.
Forensic science international, 157(1), 46-56 (2006-01-24)
A method was developed for simultaneously analyzing cocaine (COC), benzoylecgonine (BZE), norbenzoylecgonine (BNE), norcocaine (NCOC), ecgonine (ECG), ecgonine methyl ester (EME), m-hydroxybenzoylecgonine (HBZE), anhydroecgonine methyl ester (AEME), cocaethylene (CE), norcocaethylene (NCE), and ecgonine ethyl ester (EEE) in blood, urine, and
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