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Merck

371963

Hexafluoropropene, trimer

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About This Item

Linear Formula:
[CF3C(F)=CF2]3
CAS Number:
6792-31-0
Molecular Weight:
450.07
NACRES:
NA.22
PubChem Substance ID:
24863138
UNSPSC Code:
12352100
MDL number:
MFCD00043821

InChI

1S/3C3F6/c3*4-1(2(5)6)3(7,8)9

SMILES string

FC(F)=C(F)C(F)(F)F.FC(F)=C(F)C(F)(F)F.FC(F)=C(F)C(F)(F)F

InChI key

VJRSWIKVCUMTFK-UHFFFAOYSA-N

form

liquid

bp

110-115 °C (lit.)

density

1.83 g/mL at 25 °C (lit.)

functional group

fluoro

Quality Level

100

Related Categories

Application

Hexafluoropropene, trimer may be used in the preparation of photochromic spiroindolinonaphthoxazine derivative. It may be used in the preparation of 2-trifluoromethyl-3-heptadifluoroisopropyl-2-perfluoropentene-4-(N′,N′-dimethylamino propyl) imino(I).

General description

Spectra of three isomeric trimers of hexafluoropropene have been investigated. It reacts with primary amines, via indirect substitution of fluorine atoms, to form the corresponding enamines and enimines.

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

75.2 °F - closed cup

flash_point_c

24 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
STBK9975
STBK5530
STBK5036
STBK1970
STBF2489V

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Synthesis and NMR study of 9'-substituted spiroindolinonaphthoxazine derivatives.
Kakishita T, et al.
Journal of Heterocyclic Chemistry, 29(7), 1709-1715 (1992)
Interaction of hexafluoropropene trimers with ammonia and primary amines.
Del'tsova DP, et al.
Journal of Fluorine Chemistry, 79(1), 97-102 (1996)
Non-bond F? F nuclear spin couplings II. Hexafluoropropene trimers.
Cavagna F and Schumann C.
Journal of Magnetic Resonance, 22(2), 333-334 (1969)
D Findik et al.
Journal of cellular biochemistry, 57(1), 12-21 (1995-01-01)
In addition to a role for de novo protein synthesis in apoptosis we have previously shown that activation of a protein phosphatase or loss of activity of a kinase is also important in radiation-induced apoptosis in human cells [Baxter, and
J de Rooij et al.
Nature, 396(6710), 474-477 (1998-12-16)
Rap1 is a small, Ras-like GTPase that was first identified as a protein that could suppress the oncogenic transformation of cells by Ras. Rap1 is activated by several extracellular stimuli and may be involved in cellular processes such as cell
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