428426
(2-Bromoethoxy)-tert-butyldimethylsilane
99%
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About This Item
Linear Formula:
BrCH2CH2OSi(CH3)2C(CH3)3
CAS Number:
Molecular Weight:
239.23
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
99%
Form:
liquid
Quality Level
assay
99%
form
liquid
contains
Na2CO3 as stabilizer
refractive index
n20/D 1.444 (lit.)
bp
70-75 °C/2.5 mmHg (lit.)
density
1.115 g/mL at 25 °C (lit.)
functional group
bromo
storage temp.
2-8°C
SMILES string
CC(C)(C)[Si](C)(C)OCCBr
InChI
1S/C8H19BrOSi/c1-8(2,3)11(4,5)10-7-6-9/h6-7H2,1-5H3
InChI key
JBKINHFZTVLNEM-UHFFFAOYSA-N
General description
(2-Bromoethoxy)-tert-butyldimethylsilane is a silane derivative.
Application
(2-Bromoethoxy)-tert-butyldimethylsilane was used in the synthesis of 4-(3-hydroxypropyl)-4′-methyl-2,2′-bipyridine.
It may be used as a reagent for the selective N-alkylation of 5-piperazin-1-yl-1H-indole and (1H-indol-2-yl)-piperazin-1-yl-methanone and also in the synthesis of 2-[3-[(3,4,5-trimethoxyphenyl)thio]-1H-indol-5-yloxy]ethanol.
It may be used as a reagent for the selective N-alkylation of 5-piperazin-1-yl-1H-indole and (1H-indol-2-yl)-piperazin-1-yl-methanone and also in the synthesis of 2-[3-[(3,4,5-trimethoxyphenyl)thio]-1H-indol-5-yloxy]ethanol.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
163.4 °F - closed cup
flash_point_c
73 °C - closed cup
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Tetrahedron Letters, 47, 69-69 (2006)
Arylthioindole inhibitors of tubulin polymerization. 3. Biological evaluation, structure-activity relationships and molecular modeling studies.
La Regina G, et al.
Journal of Medicinal Chemistry, 50(12), 2865-2874 (2007)
Hansen, Joshua; et al.
Tetrahedron Letters, 47(1), 69-72 (2005)