901443
Trimethylphosphine solution
90% M in 2-methyltetrahydrofuran, liquid
Synonym(s):
Trimethylphosphane, PMe3, Trimethylphosphorus
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About This Item
Linear Formula:
(CH3)3P
CAS Number:
Molecular Weight:
76.08
UNSPSC Code:
12352128
NACRES:
NA.22
MDL number:
Beilstein/REAXYS Number:
969138
Product Name
Trimethylphosphine solution, 0.9 M in 2-methyltetrahydrofuran
form
liquid
Quality Level
reaction suitability
reagent type: ligand
reaction type: Mitsunobu Reaction, reagent type: ligand
reaction type: Wittig Reaction
concentration
0.9 M in 2-methyltetrahydrofuran
density
0.838 g/mL
functional group
phosphine
SMILES string
CP(C)C
InChI
1S/C3H9P/c1-4(2)3/h1-3H3
InChI key
YWWDBCBWQNCYNR-UHFFFAOYSA-N
Application
Trimethylphosphine is an electron-rich phosphine ligand used in the Mitsunobu reaction. It participates in the transformation of azides into carbamates, aziridines from azidoalcohols, iminophosphoranes and aza-Wittig reaction. This product is offered as a solution in 2-methyltetrahydrofuran for more convenient handling.
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Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
5.0 °F
flash_point_c
-15 °C
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