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Merck

D100951

N,N-Diethyl-3-methylbenzamide

97%

Synonym(s):

N,N-Diethyl-m-toluamide, m-Toluic acid diethylamide, DEET

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About This Item

Linear Formula:
CH3C6H4CON(C2H5)2
CAS Number:
134-62-3
Molecular Weight:
191.27
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24893319
EC Number:
205-149-7
Beilstein/REAXYS Number:
2046711
MDL number:
MFCD00009046
Assay:
97%
Form:
liquid

Key Documents

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InChI key

MMOXZBCLCQITDF-UHFFFAOYSA-N

InChI

1S/C12H17NO/c1-4-13(5-2)12(14)11-8-6-7-10(3)9-11/h6-9H,4-5H2,1-3H3

SMILES string

CCN(CC)C(=O)c1cccc(C)c1

vapor density

6.7 (vs air)

vapor pressure

<0.01 mmHg ( 25 °C)

assay

97%

form

liquid

Quality Level

100

bp

111 °C/1 mmHg, 160 °C/19 mmHg (lit.)

density

0.998 g/mL at 20 °C (lit.)

Related Categories

Application

N,N-Diethyl-3-methylbenzamide can undergo reduction in the presence of iron catalyst to synthesize N,N-diethyl-3-methylbenzamine.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Skin Irrit. 2

Storage Class

10 - Combustible liquids

wgk

WGK 1

flash_point_f

203.0 °F - closed cup

flash_point_c

95 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
MKCZ7566
MKCX2637
MKCW4328
MKCT6310
MKCS3756

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The insect repellent DEET (N, N-diethyl-3-methylbenzamide) increases the synthesis of glutathione S-transferase in cultured mosquito cells.
Hellestad VJ, et al.
Cell Biology and Toxicology, 27(2), 149-157 (2011)
Ivanka B Semerdjieva et al.
Molecules (Basel, Switzerland), 25(4) (2020-02-20)
Satureja pilosa Velen. senso lato is a Balkan endemic plant that is not well characterized and is found on rocky outcrops of limestone base in Stara Planina (the Balkan Mountains) and the Rhodope Mountains. The objective of this study was
Hasan Soliman Yusufoglu et al.
Saudi pharmaceutical journal : SPJ : the official publication of the Saudi Pharmaceutical Society, 26(6), 860-864 (2018-09-12)
The essential oils (EOs) of Anthemis melampodina (Am) and Anthemis scrobicularis (As) (Asteraceae) were extracted from the aerial parts of the plants by hydrodistillation, and their chemical compositions were analyzed using GC-FID and GC-MS. Fifty-six components representing 85.5% of the
S Jiang et al.
Medical and veterinary entomology, 33(3), 388-396 (2019-03-26)
Spatial repellents are an essential tool for personal protection against mosquitoes that bite and transmit disease pathogens to humans. Current repellent screening methods, such as olfactometers and alternative choice tests, are complex systems that require a relatively large quantity of
A Convenient and General Iron-Catalyzed Reduction of Amides to Amines.
Zhou S, et al.
Angewandte Chemie (International Edition in English), 121(50), 9671-9674 (2009)
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