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Merck

38912

Dimethyl ether

puriss., ≥99.9% (GC)

Synonym(s):

Methyl ether

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About This Item

Linear Formula:
(CH3)2O
CAS Number:
Molecular Weight:
46.07
UNSPSC Code:
12142100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-065-8
Beilstein/REAXYS Number:
1730743
MDL number:

Product Name

Dimethyl ether, puriss., ≥99.9% (GC)

InChI key

LCGLNKUTAGEVQW-UHFFFAOYSA-N

InChI

1S/C2H6O/c1-3-2/h1-2H3

SMILES string

COC

vapor density

1.62 (vs air)

vapor pressure

>760 mmHg ( 25 °C)

grade

puriss.

assay

≥99.9% (GC)

autoignition temp.

662 °F

expl. lim.

27 %

bp

−24.8 °C (lit.)

mp

−141 °C (lit.)

functional group

ether

Quality Level

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Application

DME can be used as a precursor for the preparation of versatile methylating agents such as dimethyl sulfate and trimethyloxonium tetrafluoroborate.

General description

Dimethyl ether (DME) is the simplest aliphatic ether used as a reactant as well as a solvent in organic synthesis. It is also used as a precursor for the preparation of important useful organic compounds such as dimethyl carbonate, methyl acetate, propylene and chloromethyl ether.

Other Notes

Sales restrictions may apply
Z742161 DIN 1 Regulator OR 99112 outlet Valve

Packaging

Cylinder with net 1.1 kg
DIN 477 nr.1

pictograms

FlameGas cylinder

signalword

Danger

hcodes

Hazard Classifications

Flam. Gas 1A - Press. Gas Liquefied gas

Storage Class

2A - Gases

wgk

WGK 1

flash_point_f

-41.8 °F - closed cup

flash_point_c

-41 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves


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Trimethyloxonium tetrafluoroborate
Curphey, TJ
Organic Syntheses, 50(4), 1019-1023 (1988)
Dimethyl ether
Muller M, et al.
Ullmann's Encyclopedia of Industrial Chemistry, 156(2), 497-511 (2000)
Direct dimethyl ether synthesis
Ogawa T, et al.
Journal of natural gas chemistry, 12(4), 219-227 (2003)
Dimethyl ether (DME) as an alternative fuel
Semelsberger TA, et al.
Journal of Power Sources, 156(2), 497-511 (2006)
Bruce L Yoder et al.
The Journal of chemical physics, 138(4), 044202-044202 (2013-02-08)
We present a new experimental configuration for the study of size-dependent, angle-resolved photoelectron and photoion spectra of weakly bound ultrafine aerosol particles targeted at particle sizes below ~20 nm. It combines single photon ionization by a tunable, table-top vacuum ultraviolet

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