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403016

Sodium chlorate

Name: Sodium chlorate
Brand: SIGALD

ACS reagent, ≥99.0%

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About This Item

Linear Formula:

NaClO₃

CAS Number:

7775-09-9

Molecular Weight:

106.44

NACRES:

NA.21

PubChem Substance ID:

329755976

UNSPSC Code:

12352302

EC Number:

231-887-4

MDL number:

MFCD00003479

Assay:

≥99.0%

Grade:

ACS reagent

Form:

powder or crystals

Solubility:

water: soluble

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Properties

grade

ACS reagent

Quality Level

200

agency

suitable for EPA 300

assay

≥99.0%

form

powder or crystals

impurities

≤0.001% N compounds, ≤0.005% insolubles

mp

248-261 °C (lit.)

solubility

water: soluble

anion traces

bromate (BrO₃^-): ≤0.015%, chloride (Cl^-): ≤0.005%, sulfate (SO₄^2-): ≤0.001%

cation traces

Ca: ≤0.005%, Fe: ≤5 ppm, K: ≤0.01%, Mg: ≤0.002%, heavy metals: ≤0.001% ((by ICP))

SMILES string

[Na+].[O-]Cl(=O)=O

InChI

1S/ClHO3.Na/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1

InChI key

YZHUMGUJCQRKBT-UHFFFAOYSA-M

Description

General description

Sodium chlorate is a hygroscopic, achiral ionic compound which on crystallization forms two enantiomeric chiral crystals. It is reported to be a probable byproduct of the drinking water disinfectant, chlorine dioxide (ClO₂). d-sodium chlorate may be utilized as chiral initiators in the synthesis of (S)-5-pyrimidyl alkanols. Commercial production of sodium chlorate is by anodic oxidation of NaCl. It finds application as herbicide, oxidizing agent and as a starting material in the synthesis of sodium perchlorate.

Application

Sodium chlorate may be used as an oxidizing agent to abstract zinc from sphalerite.

Biochem/physiol Actions

sulfation biosynthesis inhibitor

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Danger

Storage Class

5.1A - Strongly oxidizing hazardous materials

flash_point_f

Not applicable

flash_point_c

Not applicable

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Chronic 2 - Ox. Sol. 1

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Kinetics of sphalerite dissolution by sodium chlorate in hydrochloric acid.

Uca G.

Hydrometallurgy, 95(1), 39-43 (2009)

Highly enantioselective asymmetric autocatalysis induced by chiral ionic crystals of sodium chlorate and sodium bromate.

Sato I, et al.

J. Mol. Catal. A: Chem., 216(2), 209-214 (2004)

Asymmetric synthesis of optically active sodium chlorate and bromate crystals.

Pagni RM and Compton RN.

Crystal Growth & Design, 2(4), 249-253 (2002)

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