115819
2,2′-Biphenol
99%
Synonym(s):
2,2′-Biphenyldiol, 2,2′-Dihydroxybiphenyl, 2,2′-Diphenol
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About This Item
Linear Formula:
HOC6H4C6H4OH
CAS Number:
Molecular Weight:
186.21
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
217-303-0
Beilstein/REAXYS Number:
1638363
MDL number:
Quality Level
assay
99%
form
solid
bp
315 °C (lit.)
mp
108-110 °C (lit.)
SMILES string
Oc1ccccc1-c2ccccc2O
InChI
1S/C12H10O2/c13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)14/h1-8,13-14H
InChI key
IMHDGJOMLMDPJN-UHFFFAOYSA-N
Storage Class
11 - Combustible Solids
wgk
WGK 2
flash_point_f
309.2 °F - closed cup - (External MSDS)
flash_point_c
154 °C - closed cup - (External MSDS)
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Bernd Schmidt et al.
The Journal of organic chemistry, 78(17), 8680-8688 (2013-08-01)
User-friendly protocols for the protecting group-free synthesis of 2,2'-biphenols via Suzuki-Miyaura coupling of o-halophenols and o-boronophenol are presented. The reactions proceed in water in the presence of simple additives such as K2CO3, KOH, KF, or TBAF and with commercially available
Sierra Rayne et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 4(11), 876-886 (2005-10-28)
Photochemical studies on a range of model dibenzo[1,4]dioxins were performed in aqueous and organic solutions. The compounds were found to undergo a photochemically initiated aryl-ether bond homolysis that yields reactive 2-spiro-6'-cyclohexa-2',4'-dien-1'-one and subsequent 2,2'-biphenylquinone intermediates. Under steady-state irradiation, the 2,2'-biphenylquinones
W A Prütz et al.
International journal of radiation biology and related studies in physics, chemistry, and medicine, 44(2), 183-196 (1983-08-01)
Phenoxyl radicals generated pulse radiolytically by the reaction of N.3 with Gly-Tyr decay biomolecularly (2k = 4.7 X 10(8)M-1 s-1) with efficient formation of 2,2'-dimers, which enolize rapidly (k = 2.7 X 10(4) s-1) to produce the 2,2'-biphenolic product. The