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Merck

A88255

p-Anisidine

99%

Synonym(s):

4-Aminoanisole, 4-Methoxyaniline

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About This Item

Linear Formula:
CH3OC6H4NH2
CAS Number:
104-94-9
Molecular Weight:
123.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24891372
MDL number:
MFCD00007864
Beilstein/REAXYS Number:
471556
Assay:
99%
Form:
solid

Key Documents

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InChI key

BHAAPTBBJKJZER-UHFFFAOYSA-N

SMILES string

COc1ccc(N)cc1

InChI

1S/C7H9NO/c1-9-7-4-2-6(8)3-5-7/h2-5H,8H2,1H3

assay

99%

form

solid

autoignition temp.

959 °F

bp

240-243 °C (lit.)

mp

56-59 °C (lit.)

Quality Level

200

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Application

p-Anisidine can undergo aerobic oxidation in the presence of gold catalysts to form aromatic azo compounds.
p-Anisidine can be used:
  • In the diastereoselective and enantioselective synthesis of CF3-substituted azoridines catalyzed by a chiral Bronsted acid.
  • To prepare 4-organoselenium-quinolines through multi-component Povarov reaction with ethyl glyoxylate and ethynyl(phenyl)selane, catalyzed by Yb(OTf)3.
  • As a starting material to synthesize 3-fluoro-6-methoxyquinoline in two steps.,
  • To prepare N-PMP protected α-aminopropargylphosphonates by reacting with terminal alkynes and diethyl formylphosphonate hydrate using silver(I) triflate as a catalyst.

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Danger

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

flash_point_f

251.6 °F - closed cup

flash_point_c

122 °C - closed cup

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 3 - Carc. 1B - STOT RE 2

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Certificates of Analysis (COA)

Lot/Batch Number
BCCN2247
0000407458
BCCM2105
0000407458
BCCL2682

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Ytterbium (III)-catalyzed three-component reactions: synthesis of 4-organoselenium-quinolines
de Oliveira IM
New. J. Chem., 41(18), 9884-9888 (2017)
Dima A Sabbah et al.
Medicinal chemistry (Shariqah (United Arab Emirates)), 14(7), 695-708 (2018-04-14)
Phosphoinositide 3-kinase α (PI3Kα) is an attractive target for anticancer drug design. Target compounds were designed to probe the significance of alcohol and imine moieties tailored on a benzoin scaffold to better understand the structure activity relation (SAR) and improve
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Food chemistry, 221, 1308-1316 (2016-12-17)
The aim of this study was to determine the effect of boiling and roasting on the proximate, lipid oxidation, fatty acid profile and mineral content of two sesame seeds varieties. The proximate composition was significantly affected (P<0.05) during treatments. The
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Journal of microencapsulation, 34(4), 366-382 (2017-07-01)
Fish oil microcapsules were successfully prepared from fish oil-in-water emulsions using chitosan as shell material and anionic surfactants sodium dodecyl sulphate (SDS), sodium dodecylbenzenesulfonate (SDBS), sodium cholate (cholate), and sodium deoxycholate (DOC) as emulsifiers. The type of emulsifier influenced the
Zijia Li et al.
Advanced science (Weinheim, Baden-Wurttemberg, Germany), 6(6), 1802163-1802163 (2019-04-03)
Methoxy-functionalized triphenylamine-imidazole derivatives that can simultaneously work as hole transport materials (HTMs) and interface-modifiers are designed for high-performance and stable perovskite solar cells (PSCs). Satisfying the fundamental electrical and optical properties as HTMs of p-i-n planar PSCs, their energy levels
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