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Merck

1.00931

Diethyl ether

≥98% (GC), suitable for gas chromatography ECD and FID, SupraSolv®

Synonym(s):

Ethyl ether, Ether, Et2O, Ethoxyethane, Ether, Ethyl ether

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About This Item

Linear Formula:
(CH3CH2)2O
CAS Number:
Molecular Weight:
74.12
NACRES:
NA.03
EC Index Number:
200-467-2
UNSPSC Code:
12191502
MDL number:
Beilstein/REAXYS Number:
1696894
Assay:
≥98% (GC)
Technique(s):
gas chromatography (GC): suitable
Bp:
34.6 °C (lit.)
Vapor pressure:
587 hPa ( 20 °C)
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Product Name

Diethyl ether, for gas chromatography ECD and FID SupraSolv®

vapor density

2.6 (vs air)

Quality Segment

vapor pressure

587 hPa ( 20 °C)

product line

SupraSolv®

assay

≥98% (GC)

form

liquid

autoignition temp.

320 °F

potency

1215 mg/kg LD50, oral (Rat), >2000 mg/kg LD50, skin (Rabbit)

contains

~2% Ethanol as stabilizer

expl. lim.

36.5 %

technique(s)

gas chromatography (GC): suitable

refractive index

n20/D 1.3530 (lit.)

bp

34.6 °C (lit.)

mp

−116 °C (lit.)

transition temp

flash point -40 °C

density

0.706 g/mL at 25 °C (lit.)

storage temp.

15-25°C

SMILES string

CCOCC

InChI

1S/C4H10O/c1-3-5-4-2/h3-4H2,1-2H3

InChI key

RTZKZFJDLAIYFH-UHFFFAOYSA-N

General description

SupraSolv® ECD and FID is a high-purity solvent grade specifically formulated for sample preparation in gas chromatography with electron capture (ECD) and flame ionization (FID) detection.ECD and FID impose distinct and stringent solvent purity requirements. The electron capture detector is exquisitely sensitive to electronegative species — particularly halogenated compounds — at sub-nanogram concentrations, while the flame ionization detector responds to any carbon-containing organic impurity undergoing combustion. SupraSolv® ECD and FID solvents are therefore subjected to rigorous purification and detector-specific testing protocols to ensure that intrinsic solvent impurities remain below the respective detection thresholds of both detector types simultaneously.

Application

These solvents are routinely employed in PCB and organochlorine determination in water and soil, pesticide residue analysis in food and environmental matrices, dioxin screening, and hydrocarbon index measurements — applications where detector sensitivity demands the highest attainable solvent purity to ensure method selectivity and regulatory compliance.

Features and Benefits

• Dual-detector validation for both ECD and FID within a single solvent grade
• Detector-specific impurity control, targeting the precise analyte classes most detrimental to ECD (halogenated compounds) and FID (hydrocarbons and organic residues) performance, resp.
• Widest specified retention time range, guaranteeing a clean chromatographic baseline from early- to late-eluting analytes
• Batch-to-batch consistency, ensuring long-term reproducibility across routine and regulatory analytical workflows

Analysis Note

SupraSolv® ECD and FID solvents are tested and certified against stringent detector-specific purity thresholds across defined chromatographic retention time windows, including:
  • GC-ECD (early retention window): ≤ 1 ng/mL relative to tetrachloromethane
  • GC-ECD (late retention window): ≤ 2 pg/mL relative to lindane
  • GC-FID: ≤ 2 ng/mL relative to n-tetradecane

Other Notes

Explore various lab safety accessories and equipment for safe handling of solvents to increase your safety level from the first usage.

Legal Information

SUPRASOLV is a registered trademark of Merck KGaA, Darmstadt, Germany


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pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Flam. Liq. 1 - STOT SE 3

target_organs

Central nervous system

supp_hazards

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

-40.0 °F - closed cup

flash_point_c

-40 °C - closed cup



Certificates of Analysis (COA)

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