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Merck

117854

Trioctylphosphine

technical grade, 90%

Synonym(s):

TOP, P(Oct)3

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About This Item

Linear Formula:
[CH3(CH2)7]3P
CAS Number:
4731-53-7
Molecular Weight:
370.64
UNSPSC Code:
12352001
NACRES:
NA.22
PubChem Substance ID:
24847349
EC Number:
225-234-2
Beilstein/REAXYS Number:
1776995
MDL number:
MFCD00015298

Key Documents

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InChI key

RMZAYIKUYWXQPB-UHFFFAOYSA-N

InChI

1S/C24H51P/c1-4-7-10-13-16-19-22-25(23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3

SMILES string

CCCCCCCCP(CCCCCCCC)CCCCCCCC

grade

technical grade

assay

90%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

refractive index

n20/D 1.468 (lit.)

bp

284-291 °C/50 mmHg (lit.)

density

0.831 g/mL at 25 °C (lit.)

functional group

phosphine

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Application

Trioctylphosphine can be used for the conversion of metal nanocrystals, bulk powders, foils, wires, thin films to metal phosphides. It can also act as a solvent and stabilizer for synthesizing cadmium sulfide nanorods from cadmium acetate and sulfur.

Packaging

The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 2

flash_point_f

296.6 °F - closed cup

flash_point_c

147 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
MKCS5008
MKCS5007
MKCR2645
MKCR2644
MKCQ9560

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Synthesis and characterization of nearly monodisperse CdE (E= sulfur, selenium, tellurium) semiconductor nanocrystallites.
Murray C
Journal of the American Chemical Society, 115(19), 8706-8715 (1993)
Yuhuan Ji et al.
Analytical chemistry, 87(11), 5500-5504 (2015-05-07)
Bottom-up proteomics is a powerful tool for characterization of protein post-translational modifications (PTMs), where PTMs are identified at the peptide level by mass spectrometry (MS) following protein digestion. However, enzymatic digestion is associated with additional sample processing steps that may
Synthesis of cdses nanocrystals in coordinating and noncoordinating solvents: Solvent's role in evolution of the optical and structural properties.
Al-Salim N
Chemistry of Materials, 19(21), 5185-5193 (2007)
Liam R Bradshaw et al.
Nano letters, 15(2), 1315-1323 (2015-01-15)
Luminescent solar concentrators (LSCs) harvest sunlight over large areas and concentrate this energy onto photovoltaics or for other uses by transporting photons through macroscopic waveguides. Although attractive for lowering solar energy costs, LSCs remain severely limited by luminophore reabsorption losses.
Neha Arora et al.
Physical chemistry chemical physics : PCCP, 16(23), 11381-11389 (2014-05-07)
Here we present digestive ripening facilitated interatomic diffusion for the phase controlled synthesis of homogeneous intermetallic nanocrystals of Au-Sn system. Au and Sn metal nanoparticles synthesized by a solvated metal atom dispersion (SMAD) method are employed as precursors for the
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