129046
2,2,2-Trifluoroethylhydrazine solution
70 wt. % in H2O
Synonym(s):
Trifluoroethylhydrazine
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About This Item
Linear Formula:
CF3CH2NHNH2
CAS Number:
Molecular Weight:
114.07
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Form:
liquid
Product Name
2,2,2-Trifluoroethylhydrazine solution, 70 wt. % in H2O
InChI
1S/C2H5F3N2/c3-2(4,5)1-7-6/h7H,1,6H2
SMILES string
NNCC(F)(F)F
InChI key
OPMFFAOEPFATTG-UHFFFAOYSA-N
form
liquid
concentration
70 wt. % in H2O
refractive index
n20/D 1.361
transition temp
flash point 62 °C
density
1.294 g/mL at 25 °C
functional group
amine
fluoro
hydrazine
Quality Level
Related Categories
Application
2,2,2-trifluoroethylhydrazine was added to myoglobin to study its interaction with heme protein. It was also used to determine aldehydes and acetone simultaneously in water.
Building block for fluorinated pyridazines and fluoroalkyl hydrazones of β-phosphonates.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
143.6 °F
flash_point_c
62 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Journal of Fluorine Chemistry, 121, 177-177 (2003)
Synthetic Communications, 36, 2719-2719 (2006)
Karolina C Hernandes et al.
Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment, 37(1), 61-68 (2019-10-18)
Carbonyl compounds and furan derivatives may form adducts with DNA and cause oxidative stress to human cells, which establishes the carcinogenic potential of these compounds. The occurrence of these compounds may vary according to the processing characteristics of the beer.
Y S Choe et al.
The Journal of biological chemistry, 266(13), 8523-8530 (1991-05-05)
The oxidative reaction of equine myoglobin with alkylhydrazines results primarily in introduction of the alkyl group at the sterically hindered gamma-meso position. The gamma-meso adducts formed with ethyl- and n-butylhydrazine have been isolated and unambiguously identified. With high pressure liquid
Karolina C Hernandes et al.
Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment, 36(12), 1808-1821 (2019-10-10)
Compounds with toxic potential may occur in beer, such as carbonyl compounds (acetaldehyde, acrolein, ethyl carbamate [EC] and formaldehyde) and furan derivatives [furfural and furfuryl alcohol (FA)]. The objective of this study was, for the first time, to validate a
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