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About This Item
Linear Formula:
(CD3)2SO
CAS Number:
Molecular Weight:
84.17
NACRES:
NA.21
PubChem Substance ID:
eCl@ss:
39092001
UNSPSC Code:
12191502
MDL number:
Beilstein/REAXYS Number:
1237248
Isotopic purity:
99.9 atom % D
Assay:
≥99% (CP)
Mass shift:
M+6
Form:
liquid
vapor pressure
0.42 mmHg ( 20 °C)
isotopic purity
99.9 atom % D
assay
≥99% (CP)
form
liquid
autoignition temp.
573 °F
contains
1 % (v/v) TMS
expl. lim.
42 %
technique(s)
NMR: suitable
impurities
≤0.0250% water
water
refractive index
n20/D 1.476 (lit.)
bp
189 °C (lit.)
mp
20.2 °C (lit.)
density
1.190 g/mL at 25 °C (lit.)
mass shift
M+6
SMILES string
[2H]C([2H])([2H])S(=O)C([2H])([2H])[2H]
InChI
1S/C2H6OS/c1-4(2)3/h1-2H3/i1D3,2D3
InChI key
IAZDPXIOMUYVGZ-WFGJKAKNSA-N
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General description
Dimethyl sulfoxide-d6 (DMSO-d6) is a deuterated solvent and it contains 1%(v/v) TMS (Tetramethylsilane, added as a stabilizer). On photoirradiation in the range of 193 and 222nm, it undergoes decomposition to afford CD3 radicals. Quantum yields of CD3 have been evaluated by infrared diode laserabsorption spectroscopy. 100% DMSO-d6 has been used as solvent in the long-range COSY (Correlation Spectroscopy) experiment.
Application
DMSO-d6 along with glycerol or glycerol-d8 forms highly viscous binary solvents with high dissolution power for complex biological active compounds.
Other Notes
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Storage Class
10 - Combustible liquids
wgk
WGK 2
flash_point_f
190.4 °F
flash_point_c
88 °C
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Highly Viscous Binary Solvents: DMSO-d6/Glycerol and DMSO-d6/Glycerol-d8 for Polar and Apolar Mixture Analysis by NMR.
Lameiras P and Nuzillard J-M.
AZo Journal of Materials Online, 88(8), 4508-4515 (2016)
M G Nair et al.
Applied and environmental microbiology, 57(2), 434-439 (1991-02-01)
Two isoflavonoids isolated from clover roots grown under phosphate stress were characterized as formononetin (7-hydroxy,4'-methoxy isoflavone) and biochanin A (5,7-dihydroxy,4'-methoxy isoflavone). At 5 ppm, these compounds stimulated hyphal growth in vitro and root colonization of an undescribed vesicular-arbuscular mycorrhiza, a
Using high-performance quantitative NMR (HP-qNMR?) for certifying traceable and highly accurate purity values of organic reference materials with uncertainties< 0.1%.
Weber M, et al.
Accreditation and Quality Assurance, 18(2), 91-98 (2013)
Barbara Parrino et al.
European journal of medicinal chemistry, 94, 367-377 (2015-03-18)
Three new ring systems, pyrido[2',3':3,4]pyrrolo[1,2-a]quinoxalines, pyrido[3',2':3,4]pyrrolo[1,2-a]quinoxalines and pyrido[2',3':5,6]pyrazino[2,1-a]isoindoles, were synthesized through an aza-substitution on the already active isoindolo-quinoxaline system and in particular in the position 7 or 4 of the isoindole moiety and in position 5 of the quinoxaline portion.
Diode laser measurements of CD3 quantum yields and internal energy for the dissociation of dimethyl sulfoxide-d6.
Rudolph RN, et al.
J. Chem. Phys. , 106(4), 1346-1352 (1997)
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