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Merck

223328

Tungstic acid

99%

Synonym(s):

dihydroxy(dioxo)tungsten

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About This Item

Linear Formula:
H2WO4
CAS Number:
Molecular Weight:
249.85
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
231-975-2
MDL number:
Assay:
99%
Form:
powder
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Quality Level

assay

99%

form

powder

density

5.5 g/mL at 25 °C (lit.)

SMILES string

O[W](O)(=O)=O

InChI

1S/2H2O.2O.W/h2*1H2;;;/q;;;;+2/p-2

InChI key

CMPGARWFYBADJI-UHFFFAOYSA-L

General description

Tungstic acid may be prepared by either digesting tungstate of lime or by treating tungsten with hydrochloric acid. 1

Application

Starting material for the synthesis of a novel dimeric heteropolyoxopeoxotungstate which has potential in further studies of grafted polyoxoperoxo species on silica.

Packaging

5 g packaged in glass bottles; 100 g, 500 g packaged in poly bottles


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Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



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Piquemal, J-Y. et al.
Chemical Communications (Cambridge, England), 473-473 (1997)
Shaopu Liu et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 19(7), 1055-1060 (2003-07-26)
In a weak acid medium, when an isopoly-tungstic acid reacts with berberine to form an ion-association complex, strong resonance Rayleigh scattering (RRS) appears and obvious frequency-doubling scattering (FDS) as well as second-order scattering (SOS) come into being. The scattering peaks
Thierry Barré et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 61(4), 551-557 (2005-01-15)
This study is focused on the composition and the evolution of tungstate ions solutions as a function of pH and increasing concentrations. The Raman analysis showed that, during the titration of the tungstate solutions, WO4(2-), HWO4- ions and probably W2O7(2-)