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223832

Bis(triphenylphosphoranylidene)ammonium chloride

97%

Synonym(s):

Bis(triphenylphosphine)iminium chloride, Hexaphenyldiphosphazenium chloride, PPNCl

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About This Item

Linear Formula:
(C6H5)3P=N(Cl)=P(C6H5)3
CAS Number:
21050-13-5
Molecular Weight:
574.03
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
24853407
EC Number:
244-170-6
Beilstein/REAXYS Number:
4097979
MDL number:
MFCD00151523
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Quality Segment

100

assay

97%

form

powder

reaction suitability

core: ammonium

mp

270-272 °C (lit.)

SMILES string

ClP(N=P(c1ccccc1)(c2ccccc2)c3ccccc3)(c4ccccc4)(c5ccccc5)c6ccccc6

InChI

1S/C36H30ClNP2/c37-40(34-25-13-4-14-26-34,35-27-15-5-16-28-35,36-29-17-6-18-30-36)38-39(31-19-7-1-8-20-31,32-21-9-2-10-22-32)33-23-11-3-12-24-33/h1-30H

InChI key

QMTYWEYUVVWPQL-UHFFFAOYSA-N

Application

Co-catalyst used with a chiral Cobalt-salen complex for the asymmetric addition of carbon dioxide to propylene oxide.

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pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Inhalation - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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