281042
Tetradecafluorohexane
99%
Synonym(s):
Perfluorohexane
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About This Item
Linear Formula:
CF3(CF2)4CF3
CAS Number:
Molecular Weight:
338.04
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
206-585-0
Beilstein/REAXYS Number:
1802113
MDL number:
Product Name
Tetradecafluorohexane, 99%
form
liquid
InChI key
ZJIJAJXFLBMLCK-UHFFFAOYSA-N
InChI
1S/C6F14/c7-1(8,3(11,12)5(15,16)17)2(9,10)4(13,14)6(18,19)20
SMILES string
FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F
assay
99%
refractive index
n20/D 1.252 (lit.)
bp
58-60 °C (lit.)
mp
-74 °C (lit.)
density
1.669 g/mL at 25 °C (lit.)
application(s)
PFAS testing
functional group
fluoro
Quality Level
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Application
Tetradecafluorohexane has been used:
- as a fluorocarbon organic solvent in the preparation of temperature-induced phase-separation solution
- to investigate boiling heat transfer mechanisms
- as a photosensitizer in fluorous biphasic singlet oxygenation
- as a novel reaction medium for photooxidation reactions
General description
Tetradecafluorohexane in the gas phase reacts spontaneously with lithium amalgam, to give a solid and intimate mixture of lithium fluoride and elemental polymeric carbon with a small amount of superstoichiometric lithium.
hcodes
pcodes
Hazard Classifications
Aquatic Chronic 3
Storage Class
12 - Non Combustible Liquids
wgk
WGK 2
ppe
Eyeshields, Gloves
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Synthetic Communications, 26, 1861-1861 (1996)
Journal of Heat Transfer, 118, 429-429 (1996)
Journal of the American Chemical Society, 118, 5312-5312 (1996)
Michael P Grubb et al.
Nature chemistry, 8(11), 1042-1046 (2016-10-22)
Spectroscopically observing the translational and rotational motion of solute molecules in liquid solutions is typically impeded by their interactions with the solvent, which conceal spectral detail through linewidth broadening. Here we show that unique insights into solute dynamics can be
Koichi Kitaguchi et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 30(6), 687-690 (2014-06-13)
A fluorocarbon and hydrocarbon organic solvent mixture is known as a temperature-induced phase-separation solution. When a mixed solution of tetradecafluorohexane as a fluorocarbon organic solvent and hexane as a hydrocarbon organic solvent (e.g., 71:29 volume ratio) was delivered in a
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