356018
Zinc
99.9% trace metals basis, foil, thickness 0.25 mm
Synonym(s):
Zn
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About This Item
Empirical Formula (Hill Notation):
Zn
CAS Number:
Molecular Weight:
65.39
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
11101719
EC Number:
231-175-3
MDL number:
Product Name
Zinc, foil, thickness 0.25 mm, 99.9% trace metals basis
vapor pressure
1 mmHg ( 487 °C)
Quality Level
assay
99.9% trace metals basis
form
foil
reaction suitability
core: zinc, reagent type: catalyst
resistivity
5.8 μΩ-cm, 20°C
thickness
0.25 mm
bp
907 °C (lit.)
mp
420 °C (lit.)
density
7.133 g/mL at 25 °C (lit.)
SMILES string
[Zn]
InChI
1S/Zn
InChI key
HCHKCACWOHOZIP-UHFFFAOYSA-N
Application
Zinc can be used as a catalyst:
- For the reduction of nitrobenzenes to aniline derivatives in the presence of ammonium chloride.
- To synthesize β-hydroxy esters using ketones and α-bromoacetates via Reformatsky reaction.
- For the transesterification of ethyl acetate and benzyl alcohol to synthesize benzyl acetate in the presence of imidazole.
Preparation Note
- 50 × 50 mm (approximately 4.5 g)
- 100 × 100 mm (approximately 18 g)
Storage Class
11 - Combustible Solids
wgk
WGK 3
ppe
Eyeshields, Gloves, type N95 (US)
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Rapid and convenient conversion of nitroarenes to anilines under microwave conditions using nonprecious metals in mildly acidic medium
Keenan C, et al.
Synthetic Communications, 47, 1085-1089 (2017)
Transesterification reactions catalyzed by a recyclable heterogeneous zinc/imidazole catalyst
Nakatake D, et al.
advanced synthesis and catalysis, 358, 2569-2574 (2016)
Shigeki Seto et al.
Bioorganic & medicinal chemistry, 20(3), 1188-1200 (2012-01-21)
The design, synthesis, and evaluation of 6-6-7 tricyclic quinolones containing the strained spirocycle moiety aiming at the GSK-3β inhibitor were described. Among the synthesized compounds, 44, having a cyclobutane ring on a spirocycle, showed excellent GSK-3β inhibitory activity in both