62421
Lithium aluminum hydride
≥97.0% (gas-volumetric), tablet (5 g each)
Synonym(s):
LAH, Lithium alanate, Lithium tetrahydroaluminate
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About This Item
Linear Formula:
LiAlH4
CAS Number:
Molecular Weight:
37.95
NACRES:
NA.22
PubChem Substance ID:
EC Number:
240-877-9
MDL number:
UNSPSC Code:
12352306
Assay:
≥97.0% (gas-volumetric)
Form:
tablet (5 g each)
Quality Level
assay
≥97.0% (gas-volumetric)
form
tablet (5 g each)
reaction suitability
reagent type: reductant
mp
125 °C (dec.) (lit.)
SMILES string
[Li].[AlH3]
InChI
1S/Al.Li.4H/q-1;+1;;;;
InChI key
OCZDCIYGECBNKL-UHFFFAOYSA-N
Other Notes
Review
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signalword
Danger
hcodes
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1A - Water-react. 1
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H.C. Brown et al.
Tetrahedron, 35, 567-567 (1979)
Matthias D'hooghe et al.
Organic & biomolecular chemistry, 8(3), 607-615 (2010-01-22)
trans- and cis-1-Alkyl-4-aryl-3-chloroazetidin-2-ones, prepared through cyclocondensation of chloroketene and the appropriate imines in a diastereoselective way, were transformed into the corresponding non-activated trans- and cis-2-aryl-3-(hydroxymethyl)aziridines via reductive ring contraction using LiAlH(4) in Et(2)O. Furthermore, trans-2-aryl-3-(hydroxymethyl)aziridines were transformed into 2-amino-3-arylpropan-1-ols and
Sonja Stanković et al.
Organic & biomolecular chemistry, 8(19), 4266-4273 (2010-08-05)
A new synthetic protocol for the LiAlH(4)-promoted reduction of non-activated aziridines under microwave conditions was developed. Thus, ring opening of 2-(acetoxymethyl)aziridines provided the corresponding beta-amino alcohols, which were then used as eligible substrates in the synthesis of 5-methylmorpholin-2-ones via condensation