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Merck

939919

1,3-propene sultone

≥99.5%, ≤1 μmol/g acid, anhydrous, battery grade

Synonym(s):

1-propene-1,3-sultone, PES battery additive, prop-1-ene-1,3-sultone

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About This Item

Empirical Formula (Hill Notation):
C3H4O3S
CAS Number:
Molecular Weight:
120.13
UNSPSC Code:
12352100
NACRES:
NA.21
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Quality Segment

grade

anhydrous, battery grade

assay

≥99.5%

form

powder

mol wt

120.12 g/mol

impurities

≤1 μmol/g (acid), ≤1 μmol/g acid, ≤100 ppm (H2O)

bp

118 °C

mp

85 °C

solubility

soluble (carbonates: soluble(lit.)), soluble (glymes: soluble(lit.)), water: soluble (highly soluble(lit.))

application(s)

battery manufacturing
battery precursors

SMILES string

O=S1(=O)OCC=C1

InChI

1S/C3H4O3S/c4-7(5)3-1-2-6-7/h1,3H,2H2

General description

1,3-propene sultone or prop-1-ene-1,3-sultone, abbreviated PES, is a white solid at room temperature. PES is soluble in water, carbonates, glymes, and many of the polar solvents used in battery liquid electrolytes.

Application

1,3-propene sultone is commonly used as a film-forming additive in battery liquid electrolytes, at concentrations up to 3% for both lithium-ion and sodium-ion chemistries. Because prop-1-ene-1,3-sultone (PES) has a more positive reduction potential than most carbonate solvents such as propylene carbonate, PES is sacrificially reduced on the surface of the anode to form a protective and ionically conductive SEI layer. This SEI layer is particularly useful in graphite cells to inhibit the co-intercalation of carbonate into the graphite. Our battery grade PES meets specifications for high purity, low moisture, and low acid content to facilitate optimal performance of your electrolyte formulation.


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Danger

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Muta. 2 - Skin Sens. 1B

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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