33400
Bromophos-methyl
PESTANAL®, analytical standard
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About This Item
Empirical Formula (Hill Notation):
C8H8BrCl2O3PS
CAS Number:
Molecular Weight:
366.00
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
218-277-3
Beilstein/REAXYS Number:
1988276
MDL number:
grade
analytical standard
Quality Level
product line
PESTANAL®
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable, NMR: suitable, gas chromatography (GC): suitable
mp
53-56 °C
suitability
passes test for identity (NMR)
application(s)
agriculture
environmental
format
neat
storage temp.
2-8°C
SMILES string
COP(=S)(OC)Oc1cc(Cl)c(Br)cc1Cl
InChI
1S/C8H8BrCl2O3PS/c1-12-15(16,13-2)14-8-4-6(10)5(9)3-7(8)11/h3-4H,1-2H3
InChI key
NYQDCVLCJXRDSK-UHFFFAOYSA-N
General description
Bromophos-methyl is an organophosphorus insecticide widely used to control a wide variety of insects in agriculture and forestry sector.
Application
Bromophos-methyl may be used as a reference standard for the determination of bromophos-methyl in biological samples using headspace solid-phase microextraction and gas chromatography with mass spectrometric detection.
Bromophos-methyl may be used as a reference standard for the determination of the insecticidel in berries using head-space solid phase microextraction with gas chromatography coupled to mass spectrometry (SPME-GC-MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Other Notes
Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
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signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Headspace solid-phase microextraction in combination with gas chromatography-mass spectrometry for the rapid screening of organophosphorus insecticide residues in strawberries and cherries.
Lambropoulou AD and Albanis AT
Journal of Chromatography A, 993(1-2), 197-203 (2003)
Insecticide residues in milled fractions of dry or tough wheat treated with malathion, bromophos, iodofenphos, and pirimiphos-methyl.
G W Mensah et al.
Journal of economic entomology, 72(5), 728-731 (1979-10-15)
J L Willems et al.
Archives of toxicology, 67(2), 79-84 (1993-01-01)
We measured in nine patients, poisoned by organophosphorus agents (ethyl parathion, ethyl and methyl parathion, dimethoate, or bromophos), erythrocyte and serum cholinesterase activities, and plasma concentrations of the organophosphorus agent. These patients were treated with pralidoxime methylsulphate (Contrathion), administered as